专利摘要:
The invention relates to cleaning and / or care agents for damaged keratin fibers which contain a combination of at least one dicarboxylic acid having 2 to 10 carbon atoms and at least one selected amino acid, and method of cleaning and / or care of keratin fibers comprising such agents.
公开号:FR3043912A1
申请号:FR1661113
申请日:2016-11-17
公开日:2017-05-26
发明作者:Thomas Hippe；Astrid Kleen-Fehres；Hartmut Manneck
申请人:Henkel AG and Co KGaA；
IPC主号:

专利说明:

The invention relates to cleaning and / or care agents for damaged keratin fibers which contain a combination of at least one dicarboxylic acid having 2 to 10 carbon atoms and at least one selected amino acid, and method of cleaning and / or care of keratin fibers comprising such agents.
Keratin fibers, especially the hair, are solid components of the human body and important components of clothing and home textiles in humans, and play an important role in everyday life. Treatment with washing, cleaning, styling and coloring products, for cleaning and shaping purposes, and exposure to environmental influences, such as ozone, salt and chlorine water, and IR, UV and thermal radiation (drying) leads over time to cumulative damage to the fibers and therefore a decrease in their quality. For example, hair cleaning with shampoos as well as decorative shaping of the hairstyle by coloring or permanent waving are operations that affect the natural structure and properties of the hair. As a result, for example combing on wet and dry hair, the strength, thickness, shine and feel of the hair can not be satisfactory after such treatment. In the case of colored hair, the holding of the color on the hair may also be insufficient especially when the hair is washed frequently so that it gradually occurs a color disgorging. It is especially because of the strong stress of the hair, for example the coloring or the realization of perms as well as the cleaning of the hair with shampoos and the environmental pollution, that the products of care having a sufficiently strong and the most durable effect possible have gained importance. Such care agents influence the natural structure and properties of the hair. Thus, such treatments then make it possible, for example, to improve the combing ability of wet and dry hair, the strength and thickness of the hair or to prevent the increase in the number of split ends of the hair.
Therefore, it has long been in use to subject the hair to a special after-treatment which most often consists of treating the hair, in the form of a rinse, with particular active substances, for example salts of quaternary ammonium or special polymers. This treatment makes it possible, according to the formulation, to improve the combing, the hold and the thickness of the hair and to reduce the number of split ends.
Care additives and film-forming agents are frequently added to perming agents without significantly improving the hair structure. High molecular weight polymers which take on the upper layer of the skin and hair, where they generate subjectively better outer hair, are used for this purpose. Structural damage to the interior of the hair, which is mainly caused by the reduction process when performing perms, can not be reduced in this way because, due to their size, the substances can not penetrate in the hair. In addition, the durability of the effects of the structural improving additives is often unsatisfactory because they adhere only superficially to the hair.
It has already been attempted to remedy this problem by polymerizing monomeric compounds directly on the hair. Thus, according to US 5,362,486, specific urethane oligomers comprising terminal acrylate or bisulfite groups are applied to the hair and then polymerized to form polymers adhering in situ to the hair. This method allows to influence the surface properties of the hair in an appropriate manner, such as volume, brightness, hold, combing and resistance to moisture and pollutants absorption of air and to the loss of color of the hair. In the process, there is a radical polymerization on the hair, i.e. the hair needs radical formers such as benzoyl peroxide.
The patent application WO 2005 / 115314A1 discloses a process for restructuring keratin fibers in which the keratin fibers are brought into contact with cystine and with at least one dicarboxylic acid having 2 to 10 carbon atoms; the preferred dicarboxylic acids are chosen from oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, maleic acid, and acid. fumaric and sorbic acid and succinic acid is particularly preferred. The patent application DE 10051774 A1 describes the use of short-chain carboxylic acids having a molecular weight of less than 750 g / mol in cosmetic agents as active substance for the restructuring of keratin fibers. Patent Application EP1174112A discloses hair treatment agents which contain, in addition to an organic acid, as other obligatory constituents an organic solvent, a cationic surfactant and a higher alcohol and which are used for the repair of the pores of the hair.
The object of the invention was to propose a process for the restructuring of keratin fibers which has advantages over the state of the art and which allows sufficient efficiency and duration of action. The process must be carried out not only under fiber-friendly conditions, but must also be physiologically harmless and be carried out for example without the use of reactive monomers.
Surprisingly, it has been found that the use of a combination of at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and at least one selected amino acid of the formula (VI), as explained in subsequently, improves the tensile extension properties of keratin fibers and increases their resistance. In the context of the present invention, it has been found that the use of agents, compositions and methods of the invention makes it possible to modify the internal and external structure of the keratin fibers, that is to say that it allows the restructuring of keratin fibers. For the purposes of the present invention, restructuring is understood to mean, in particular, a reinforcement of the fibers, an increase in the resistance to tearing and / or a reduction in the damages of the keratin fibers due to the most diverse influences. Here, for example, the restoration of natural resistance plays an important role. The restructured fibers may for example be characterized by an increased melting point (by DSC measurement), increased tear strength, increased strength, greater elasticity and / or greater volume, which may be reflected, for example, by a more abundant hairstyle. In addition, they may have improved luster, better feel, and / or greater ease of combing.
By keratin fibers is meant according to the invention the skins, wool, feathers, silk and hair, but especially human hair.
By cleaning agents is meant according to the invention in particular shampoos but also preparations for the shower, washing creams and makeup removers.
The term "care agents" according to the invention in particular means hair conditioning agents, capillary rinsing agents, hair conditioning agents, revitalizing agents without rinsing and capillary sprays.
The object of the invention is achieved by agents, compositions and methods according to the claims.
A first subject of the present invention is therefore a cosmetic agent for cleaning and / or caring for keratin fibers, in particular human hair, which is free of peroxide compounds, containing a) at least one saturated dicarboxylic acid having from 2 to 10 carbon atoms and / or at least one salt of this acid or acids, furthermore b) at least one amino acid of the formula (VI)
(VI) wherein X represents a hydrogen atom or a monovalent or divalent cation; n is zero, 1, 2 or 3; R 1 represents a radical which is selected from an amino group, a guanidine group, a (1H-imidazol-4-yl) group, a carboxylic acid amide group -CONH 2, a 1H-indol-3-yl group, a thiol group, -SH and a methylsulfanyl -SCH3 group, or at least one salt of this amino acid, in addition c) at least one active cleaning and / or care substance, selected from surfactants, fatty alcohols and oils.
Dicarboxylic acids saturated with 2 to 10 carbon atoms and / or at least one salt of this acid or acids
The saturated dicarboxylic acids which are preferred according to the invention, having 2 to 10 carbon atoms, are chosen from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid and pimelic acid. , suberic acid, azelaic acid, sebacic acid, and mixtures of these acids. According to the invention, succinic acid and malic acid and mixtures thereof are particularly preferred. According to the invention, succinic acid is even more preferred. The dicarboxylic acids mentioned make a significant contribution to the restructuring effect of the cleaning and / or care agents of the invention. Optically active malic acid can be used both in the form of D-malic acid, L-malic acid or racemic DL-malic acid. For cost reasons, DL-malic acid is preferred.
Depending on the pH value of the cleaning and / or care agent of the invention or the composition (A) of the invention used in one of the cleaning and / or care processes, the at least one a saturated dicarboxylic acid having 2 to 10 carbon atoms may be present as undissociated, partially dissociated or fully dissociated acid. If the at least one saturated dicarboxylic acid having 2 to 10 carbon atoms is present in the partially dissociated or completely dissociated form, the counterion is chosen from physiologically acceptable cations, such as in particular the alkali metal ions, alkaline earth metal and zinc as well as ammonium, alkylammonium, alkanolammonium and glucammonium ions, in particular mono-, di- and trimethylamine, -ethyl- and -hydroxyethylammonium ions. Particularly preferred are the salts of saturated dicarboxylic acids having 2 to 10 carbon atoms with C 1 -C 6 aminoalkanols, especially monoethanolamine, and C 1 -C 6 aminoalkanediols, especially 2-amino-2-one. methylpropan-1-ol, 2-amino-2-methylpropane-1,3-diol, 2-amino-propan-1-ol, 3-amino-propan-1-ol, 1-aminopropanol-2 ol (MIPA) and 2-amino-2- (hydroxymethyl) propane-1,3-diol (TRIS), the salts with monoethanolamine, 2-amino-2-methylpropan-1-ol and 2-amino- 2-methylpropane-1,3-diol being particularly preferred.
Sodium, potassium, magnesium, ammonium and monoethanolammonium ions are extraordinarily preferred as counterions for partially or fully dissociated saturated dicarboxylic acids having 2 to 10 carbon atoms. In addition, however, it is also possible to use saturated dicarboxylic acids having 2 to 10 carbon atoms neutralized with amino acids with alkaline reaction such as for example arginine, lysine, ornithine and histidine.
Sodium, potassium, ammonium, monoethanolammonium, lysine and arginine salts and mixtures thereof are preferred salts of saturated dicarboxylic acids having 2 to 10 carbon atoms.
The preferred cleaning and / or care agents according to the invention contain the at least one saturated dicarboxylic acid having 2 to 10 carbon atoms or one or more of its salts in a total amount of 0.05 to 6% by weight. preferably 0.1 to 4% by weight, more preferably 0.5 to 2.5% by weight, each converted to the undissociated acid and based on the weight of the cleaning agent and / or care.
Although the dicarboxylic acids are present in the salt form, the above quantitative data refer to the respective dicarboxylic acid in undissociated form so as not to distort the quantitative data by molecular weights other than salts. A weighed amount of 15% by weight of disodium succinate hexahydrate would give, for example, a succinic acid concentration of 6.55% by weight converted.
Amino acid of the formula A / h The restructuring effect of the cleaning and / or care agents of the invention is mainly due to the above-mentioned dicarboxylic acids in combination with at least one selected amino acid of the formula (VI).
Therefore, the cleaning agents and / or care of the invention further contain as another mandatory component at least one amino acid of the formula (VI)
(VI) wherein X represents a hydrogen atom or a monovalent or divalent cation; n is zero, 1.2 or 3; R1 represents a radical which is selected from an amino group, a guanidine group, a (IZ-f-imidazoM-yl) group, a carboxylic acid amide group -CONH2, a 1 / - / - indol-3- group. yl, a thiol group -SH and a methylsulfanyl group -SCH3, or at least one salt of this amino acid.
Preferred amino acids of formula (VI) are selected from arginine, lysine, histidine, asparagine, glutamine, cysteine, methionine, tryptophan, and mixtures thereof. The particularly preferred cleaning and / or care agents according to the invention contain mixtures of arginine and lysine or at least one salt of these amino acids.
The preferred cleaning and / or care agents of the invention contain the at least one amino acid of the formula (VI) or one or more of their salts in a total amount of 0.05 to 3% by weight, preferably from 0.1 to 2.5% by weight, particularly preferably from 0.3 to 1.2% by weight, each time converted to the undissociated acid and on the basis of the weight of the cleaning and / or care. Other particularly preferred cleaning and / or care agents of the invention contain mixtures of arginine and lysine, or at least one salt of these amino acids in a total amount of 0.05 to 3% by weight. weight, preferably from 0.1 to 2.5% by weight, particularly preferably from 0.3 to 1.2% by weight, in each case converted to the undissociated acid and on the basis of the weight of the cleaning and / or care agent.
Cleaning and care agents Surfactants
The cleaning agents of the invention are surfactants and emulsifiers. The terms "surfactants" and "emulsifiers" refer to active substances at the surface which form absorption layers at interfaces and boundary surfaces or which can aggregate in volume phases to form colloid micelles or lyotropic mesophases. The main characteristics of surfactants and emulsifiers are directed absorption at boundary surfaces and micelle aggregation and lyotropic phase formation. A distinction is made between anionic surfactants consisting of a hydrophobic radical and a negatively charged hydrophilic head group, amphoteric surfactants which carry a negative charge and a positive compensation charge, and cationic surfactants which comprise in addition to a radical hydrophobic a positively charged hydrophilic group and nonionic surfactants which have no charge, but have strong dipolar moments and are highly hydrated in aqueous solution.
The cleaning and / or care agents which are preferred according to the invention contain at least one surfactant in a total amount of from 0.1 to 30%, preferably from 0.5 to 20% by weight, particularly preferably from 1 to 15% by weight, more preferably 3 to 10% by weight, more preferably 5 to 7% by weight, based on the weight of the cleaning and / or care agent.
All anionic surfactant substances, suitable for use on the human body, are suitable anionic surfactants in the cleaning and / or care agents of the invention. These substances are characterized by a water-soluble anionic group such as a carboxylate, sulphate, sulphonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, the molecule may contain glycol ether or polyglycol ether groups, ester, ether and amide groups as well as hydroxyl groups. Examples of suitable anionic surfactants are each in the form of sodium, potassium and ammonium salts as well as salts of mono-, di- and trialkanolammonium having 2 to 4 carbon atoms in the alkanol group, fatty acids and the like. linear and branched compounds having 8 to 30 carbon atoms (soaps), carboxylic acid ethers of the formula R-O- (CH 2 -CH 2 O) x -CH 2 -COOH wherein R is a linear alkyl group having 8 to 30 atoms carbon and x = 0 or 1 to 16, acylsarcosides having 8 to 24 carbon atoms in the acyl group, acyltaurides having 8 to 24 carbon atoms in the acyl group, acylisethionates having 8 to 24 carbon atoms in the acyl group; acyl group, monoesters and dialkylsters of sulfosuccinic acid having 8 to 24 carbon atoms in the alkyl group and a monoalkylpolyoxyethyl ester of sulfosuccinic acid having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, sulfonates of linear alkane having 8 to 24 carbon atoms, linear alpha-olefin sulfonates having 8 to 24 carbon atoms, alpha-sulfofatty acid methyl esters with fatty acids having 8 to 30 carbon atoms, sulfates alkyl and alkylpolyglycol ethersulfates of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, wherein R is a preferably linear alkyl group having 8 to 30 carbon atoms and x = 0 or 1 to 12, mixtures of surfactant hydroxysulphonates according to DE-A-37 25 030, hydroxyalkylpolyethylene ethers and / or hydroxyalkylene-propylene glycol sulfates according to German Laid-Open Patent Application No. 37 23 354, unsaturated fatty acid sulphonates having from 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344, esters of tartaric acid and citric acid with alcohols which represent adducts of about 2 to 15 molecules of ethylene oxide and / or propylene oxide to fatty alcohols having 8 to 22 carbon atoms, alkyl ether and / or alkenyl ether phosphates of the formula (II), R1 (OCH2CH2) n-O-P (O) (OX) (OR2) (II), wherein R1 represents preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R2 is hydrogen, a radical (CH2CH2O) nR1 or X, n is a number from 1 to 10 and X represents hydrogen, an alkali metal or a metal alkaline earth metal or a group NR3R4R5R6, R3 to R6 independently represent hydrogen or a group C1-C4 hydrocarbon radical, alkyleneglykol esters sulfated with fatty acids of the formula (XII) R7CO (Alko) nSO3M (XII) in which R7CO- represents an unsaturated and / or saturated, aliphatic, linear or branched acyl radical having from 6 to 22 carbon atoms, Alk represents a CH2CH2> CHCH3CH2 group and / or CH2CHCH3i n is a number from 0.5 to 5 and M is a cation, as described in DE19736906, sulphates of monoglyceride and monoglyceride ether of the formula (XIII) <: η2ο (<: η2 <: η2ο), - cor8
I
CH0 (CH2CH20) yH
Wherein R8CO represents a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z represents in total 0 or numbers ranging from 1 to 30, preferably from 2 to 10 and X represents an alkali metal or alkaline earth metal.
Typical examples of monoglyceride (ether) sulphates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Advantageously, the monoglyceride sulphates of the formula (XIII) in which R8CO represents a linear acyl group having 8 to 18 carbon atoms, such as those described in EP-B1 0 561 825, EP-B1 0 561 999, are advantageously used. , DE-A1 42 04 700 or the documents of AK Biswas et al. in J.Am.Oil.Chem.Soc. 37 * 171 (1960) and in F.U.Ahmed in J.Am.Oil.Chem.Soc. 67 * 8 (1990), amidether carboxylic acids, such as those described in EP 0 690044, the products of condensation of C 8 -C 20 fatty acids with amino acids, such as sodium cocoylglutamate, and / or with protein hydrolysates which are known to those skilled in the art such as, for example, protein fatty acid condensation products.
The preferred anionic surfactants are the alkylpolyglycol ether sulfates and ether carboxylic acids each having 10 to 18 carbon atoms in the alkyl group and 2 to 6 ethylene oxide groups in the molecule, the isethionates of acyl group having 8 to 24 carbon atoms in the acyl group, as well as acylated amino acids and fatty acid condensation products of proteins having 8 to 24 carbon atoms in the acyl group and mixtures of these anionic surfactants.
The preferred cleaning agents according to the invention contain at least one anionic surfactant in a total amount of 0.1 to 30% by weight, preferably 0.5 to 20% by weight, particularly preferably 1 to 15% by weight. by weight, still more preferably 3 to 10% by weight, more preferably 5 to 7% by weight, in each case based on the weight of the cleaning agent. But also the preferred care agents according to the invention contain at least one anionic surfactant, but in lower total amounts of from 0.01 to 10% by weight, preferably from 0.1 to 5% by weight, particularly preferably preferred from 0.5 to 3% by weight, each based on the weight of the care agent.
Zwitterionic surfactants refer to surface-active compounds whose molecule contains at least one quaternary ammonium group and at least one -COO () - or -SO3 (-) group. Especially suitable zwitterionic surfactants are so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example coco-alkyl dimethyl ammonium glycinate, N-acyl aminopropyl glycinates. N, N-dimethylammonium, for example cocoacylaminopropyl-dimethylammonium glycinate and 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines each having from 8 to 18 carbon atoms in the alkyl or acyl group and also the cocoacylaminoethylhydroxyethylcarboxymethyl glycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known as INCI Cocamidopropyl Betaine.
The preferred cleaning agents according to the invention contain at least one zwitterionic surfactant in a total amount of 0.1 to 15% by weight, preferably 0.2 to 10% by weight, particularly preferably 0.5 to 8% by weight, still more preferably 1 to 5% by weight, more preferably 2 to 4% by weight, in each case based on the weight of the cleaning agent. But also the preferred care agents according to the invention contain at least one zwitterionic surfactant, however in lower total amounts of from 0.01 to 7% by weight, preferably from 0.1 to 5% by weight, so particularly preferably from 0.1 to 3% by weight, each based on the weight of the care agent.
Ampholytic surfactants are understood to mean surface-active compounds whose molecule contains, apart from an acyl or C8-C24 alkyl group, at least one free amino group and at least one -COOH- group or a -SO3H group and which are able to form internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyl acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglyines, N-alkyl-taurines, N alkylsarcosines, 2-aminopropionic acids and alkylaminoacetic acids having 8 to 24 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylamiopropionate and C12-C18 acyl sarcosine.
The preferred cleaning agents according to the invention contain at least one ampholytic surfactant in a total amount of 0.1 to 10% by weight, preferably 0.2 to 8% by weight, particularly preferably 0.5 to 6% by weight, still more preferably 1 to 5% by weight, more preferably 2 to 4% by weight, in each case based on the weight of the cleaning agent. However, the treatment agents which are also preferred according to the invention contain at least one ampholytic surfactant, but in total amounts of from 0.01 to 7% by weight, preferably from 0.1 to 5% by weight, in particular preferably from 0.1 to 3% by weight, in each case based on the weight of the care agent.
The nonionic surfactants preferably contain a polyol group, one or more polyalkylene glycol ether groups, in particular one or more polyethylene glycol ether groups or a combination of polyol group and polyglycol group. Preferred nonionic surfactants are, for example, adducts of from 2 to 50 moles of ethylene oxide and / or from 0 to 5 moles of propylene oxide to linear or branched fatty alcohols having from 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group, adducts, closed end groups methyl or alkyl C2 to Οβ from 2 to 50 moles of ethylene oxide and / or from 0 to 5 moles of propylene oxide to linear or branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms. and alkylphenols having 8 to 15 carbon atoms in the alkyl group, monoesters and diesters of C 12 to C 30 fatty acids, adducts of from 1 to 30 moles of ethylene oxide to glycerol, adducts of 5 to 60 moles of ethylene oxide to ri oil and hydrogenated castor oil, alkoxylated triglycerides, in particular ethoxylated, alkoxylated fatty acid alkyl esters of the formula (XIV) R1CO- (OCH2CHR2) wOR3 (XIV), wherein R1CO represents a linear acyl radical or branched, saturated and / or unsaturated having 6 to 22 carbon atoms, R2 is hydrogen or methyl, R3 is linear or branched alkyl having 1 to 4 carbon atoms, and w is 1 to 20 , amine oxides, mixed hydroxyethers, as described, for example, in DEOS 19738866, esters of fatty acids and of sorbitan and ethylene oxide adducts to fatty acid esters and of sorbitan, e.g. polysorbates, fatty acid esters and sugar and ethylene oxide adducts to fatty acid esters of sugar, ethylene oxide adducts to alkanolamides of fatty acids and amines fatty acids, alkyloligoglycoside sugar surfactants and alkenyloligoglycoside of the formula (XV), R40- [G] p (XV) wherein R4 is an alkyl or aryl radical having 4 to 22 carbon atoms, G represents a radical sugar having 5 or 6 carbon atoms and p represents numbers from 1 to 10. They can be obtained by the appropriate methods of the organic chemistry of the preparations.
The alkyloligoglycosides and alkenyloligoglycosides may be derived from aldoses or ketoses having 5 or 6 carbon atoms, preferably glucose. The preferred alkyloligoglycosides and alkenyloligoglycosides are thus alkyloligoglucosides and alkenyloligoglucosides. The index p in the general formula (XV) indicates the degree of oligomerization (DP), that is to say the distribution of mono- and oligoglycosides, and is a number between 1 and 10. While p in the individual molecule must always be whole and can take here mainly the values p = 1 to 6, the value p for a determined alkyloligoglycoside is an analytically determined calculated quantity which is generally a fractional number. Advantageously, alkyloligoglycosides and alkenyloligoglycosides are used which have a mean degree of oligomerization p of 1.1 to 3.0. From the point of view of the applications, alkyloligoglycosides and alkenyloligoglycosides are preferred in which the degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4. The alkyl or alkenyl radical R4 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as those obtained, for example, in the hydrogenation of methyl esters of fatty acids. or during the hydrogenation of aldehydes from Roelen's oxosynthesis. The preferred alkyloligoglucosides are those which have a C8 to C10 chain length (DP = 1 to 3) which are produced as light ends upon separation by distillation of C 8 to C 18 coconut fatty alcohol and may be contaminated with proportion of less than 6% by weight of C12 alcohol as well as alkyloligoglucosides on the basis of oxoalcohols in C9 / n techniques (DP = 1 to 3). The alkyl or alkenyl radical R15 may also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidic alcohol, petroselic alcohol, alcohol, and the like. arachyl alcohol, gadoleic alcohol, behenic alcohol, erucic alcohol, brassic alcohol, and their technical mixtures which can be obtained as described above. The alkyloligoglucosides based on hydrogenated C 12/14 coconut alcohol having a DP 1 to 3 are preferred. N-alkylpolyhydroxyalkyl fatty acid sugar surfactants, a nonionic surfactant of the formula (VII),
(VII) wherein R5CO represents an aliphatic acyl radical having 6 to 22 carbon atoms, R6 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] represents a linear or branched polyhydroxyalkyl radical having 3 to 12 carbon atoms and 3 to 10 hydroxyl groups. The N-alkylpolyhydroxyalkylamides of fatty acids are known substances which can generally be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine followed by acylation with a fatty acid, an alkyl ester of fatty acid or a fatty acid chloride. With regard to the production method thereof, reference is made to US Pat. Nos. 1,985,424, 2,016,962 and 2,703,798 and WO 92/06984. Advantageously, the N-alkylpolyhydroxyalkylamides of fatty acids are derived from reducing sugars having 5 or 6 carbon atoms, in particular glucose. The preferred N-alkylpolyhydroxyalkylamides of fatty acids are the N-alkylglucamide of fatty acids, such as those represented by the formula (VIII):
(VIII)
N-alkylpolyhydroxyalkyl fatty acid amides are preferably used as formula (VIII) in which R8 is hydrogen or alkyl and R7CO is acyl of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linolenic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures. The preferred fatty acid N-alkylpolyhydroxyalkylamide of formula (VIII) are those obtained by reductive amination of glucose with methylamine followed by acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative. The polyhydroxyalkylamides may furthermore be derived from maltose and palatinose.
The preferred nonionic surfactants are alkylene oxide adducts to saturated linear fatty alcohols and fatty acids each having 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. . Preparations having excellent properties are also obtained when they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
These compounds are characterized by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and can be linear or branched. Preferred are primary linear and methyl-branched aliphatic radicals at the 2-position. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and the 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. When the so-called "oxo-alcohols" are used as starting materials, the compounds having an odd number of carbon atoms in the alkyl chain are predominant.
The most preferred nonionic surfactants are, in addition, sugar surfactants. These may be contained in the cleaning and / or care agents of the invention in amounts ranging from 0.1 to 20% by weight, based on the total agent. Amounts of 0.5 to 15% by weight are preferred, and amounts of 0.5 to 7.5% by weight are most preferred.
Compounds which contain alkyl groups and which are used as surfactants may be single substances. However, it is generally preferable in the production of these materials to start from vegetable or animal raw materials so that mixtures of substances having different alkyl chain lengths which depend on the particular raw material are obtained.
In the case of surfactants which represent adducts of ethylene oxide and / or propylene oxide to fatty alcohols or derivatives of these adducts, products having a distribution of homologues may be used. "Normal" and those with a "restricted" counterpart distribution. By "normal" homologue distribution are meant homologous mixtures obtained as catalysts in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alcohols. of alkali metals. Restricted homologous distributions, on the other hand, are obtained when, for example, hydrotalcites, alkaline earth metal salts, carboxylic acids, ethers, oxides, hydroxides or alkoxides are used as catalysts. alkaline earth metals. The use of products having a restricted homolog distribution may be preferred.
The preferred cleaning agents according to the invention contain at least one nonionic surfactant in a total amount of 0.01 to 10% by weight, preferably 0.1 to 8% by weight, particularly preferably 0.2% by weight. at 6% by weight, more preferably from 0.5 to 5% by weight, still more preferably from 1 to 3% by weight, in each case based on the weight of the cleaning agent. However, the care agents which are also preferred according to the invention contain at least one nonionic surfactant, preferably in total amounts of from 0.01 to 7% by weight, preferably from 0.1 to 5%, particularly preferably from 0.1 to 3% by weight, in each case based on the weight of the care agent.
To obtain an optimal cleaning result, it is preferred to use mixtures of different types of surfactants. The preferred cleaning agents of the invention contain mixtures of at least one anionic surfactant and at least one zwitterionic surfactant. Other preferred cleaning agents of the invention contain mixtures of at least one anionic surfactant and at least one ampholytic surfactant. Other preferred cleaning agents of the invention contain mixtures of at least one anionic surfactant, at least one zwitterionic surfactant and at least one nonionic surfactant.
Suitable cationic surfactants in the cleaning and / or care agent of the invention are in principle all surface-active cationic substances which are suitable for use on the human body. These are characterized by at least one cationic water-solubilising group, such as, for example, a quaternary ammonium group, or by at least one cationic water-soluble group, for example an amine group and in addition at least one lipophilic alkyl group having about 6 to 30 carbon atoms, or by at least one imidazole group or at least one imidazylalkyl group.
The cleaning and / or care agents, in particular the care agents, of the invention which are preferred contain at least one cationic surfactant which is preferably chosen from quaternary ammonium compounds having at least one C8 alkyl radical. at C24, the esterquats and amidoamines each having at least one C8-C24 acyl radical, and mixtures thereof.
The preferred quaternary ammonium compounds having at least one C8 to C24 alkyl radical are ammonium halides, in particular chlorides, and ammonium alkyl sulphates, C8 to C24 alkyltrimethylammonium chloride, and dialkyldimethylammonium chloride. C8 to C24 and C8 to C24 trialkylmethylammonium chloride, for example cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, and the like. imidazolium compounds known under the names INCI Quaternium-27, Quaternium-83, Quaternium-87 and Quaternium-91. The alkyl chains of the aforementioned surfactants preferably have 8 to 24 carbon atoms.
The esterquats are cationic surfactants containing at least one ester function and at least one quaternary ammonium group as the structural element and further at least one C8-C24 alkyl or C8-C24 acyl group. The preferred esterquats are quaternized fatty acid ester salts with triethanolamine, quaternized fatty acid ester salts with diethanolalkylamines, and quaternized fatty acid ester salts with 1,2-dihydroxypropyldialkylmines. Such products are marketed for example under the name Stepantex®, Dehyquart® and Armocare®. N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, distearoylethyl-dimonium methosulfate and distearoylethyl hydroxyethylmonium methosulfate are preferred examples of such esterquats.
The alkylamidoamines are usually produced by amidation of natural or synthetic C8-C24 fatty acids and fatty acid moieties with C1 to C3 dialkylaminoamines. A particularly suitable compound according to the invention consisting of this group of substances is stearamido-propyldimethylamine.
The preferred care agents according to the invention contain at least one cationic surfactant in a total amount of from 0.01 to 8% by weight, preferably from 0.1 to 6% by weight, particularly preferably from 0.5 to 5% by weight, more preferably from 1.0 to 4% by weight, most preferably from 1.5 to 3.5% by weight, in each case based on the weight of the care agent . However, the preferred care agents according to the invention contain at least one cationic surfactant, preferably in a total amount of 0.01 to 2% by weight, preferably 0.1 to 1% by weight, particularly preferably from 0.2 to 0.5% by weight, in each case based on the weight of the cleaning agent.
Fatty Alcohols Other cleaning and / or care agents, in particular the care agents, which are preferred according to the invention are characterized in that at least one linear saturated 1-alkanol having 12 to 30 carbon atoms is preferably in a total amount of 0.2 to 10% by weight, in particular preferably 0.5 to 7% by weight, in each case based on the weight of the cleaning and / or care agent. These linear saturated 1-alkanols are also referred to as fatty alcohols. The at least one preferred linear saturated 1-alkanol is one which has 12 to 30 carbon atoms selected from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidic alcohol and the like. behenyl alcohol, and mixtures of these 1-alkanols, most preferably selected from cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and mixtures of cetyl alcohol / stearyl alcohol.
The preferred cleaning and / or care agents according to the invention contain, in each case with respect to their weight, at least one linear saturated 1-alkanol having 12 to 30 carbon atoms in a total amount of from 0.2 to 10. % by weight, preferably in a total amount of 0.5 to 7% by weight, at least 1-alkanol selected from cetyl alcohol, stearyl alcohol, behenyl alcohol and cetyl alcohol mixtures stearyl alcohol, being contained.
Oils
Oily natural and synthetic cosmetic bodies, which represent active care substances according to the invention, are in particular: vegetable oils. Examples of preferred vegetable oils are sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, coconut oil, orange, wheat germ oil, peach kernel oil and liquid fractions of coconut oil. However, other triglyceride oils, for example liquid beef tallow fractions (animal) as well as synthetic triglyceride oils, especially C8-C10 triglycerides, are also suitable. liquid paraffin oils, isoparaffin oils, synthetic hydrocarbons and di-n-alkyl ethers having a total of 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, for example di-n octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether as well as di-tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert -dutyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether. The compounds 1,3-di- (2-ethylhexyl) -cyclohexane (Cetiol® S) and di-n-octylether (Cetiol® OE) may be preferred. Other cosmetic oils, which are preferred according to the invention, are chosen from silicone oils which comprise, for example, dialkylsiloxanes and alkylarylsiloxanes such as cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyl- disiloxane, octamethyltrisiloxane and decamethyltetrasiloxane. The preferred volatile silicone oils may be those which may be cyclic, such as, for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane, and mixtures thereof, such as those contained in the commercially available products DC 244, 245, 344. and 345 from Dow Corning. Also suitable are volatile linear silicone oils, in particular hexamethyldisiloxane (L2), octamethyl-trisiloxane (La), decamethyltetrasiloxane (U) and any two or three component mixtures of L2, L3 and / or U preferably mixtures such as those contained in Dow Corning's commercial DC 2-1184, Dow Corning®200 (0.65 cSt), and Dow Corning®200 (1.5 cSt) products. Preferred nonvolatile silicone oils are selected from high molecular weight linear dimethylpolysiloxanes which are commercially available for example as Dow Corning®190, Dow Corning®200 Fluid having a kinematic viscosity (25 ° C) in the range from 5 to 100 cSt, preferably 5 to 50 cSt or 5 to 10 cSt and dimethylpolysiloxane having a kinematic viscosity (25 ° C) of about 350 cSt.
It may be extremely preferred according to the invention to use mixtures of the aforementioned oils.
The cleaning agents and / or care agents, especially the care agents, which are preferred according to the invention comprise, in each case with respect to their weight, at least one oil in a total amount of 0.01 to 98% by weight, preferably from 0.1 to 50% by weight, particularly preferably from 0.5 to 10% by weight, still more preferably from 1 to 3% by weight, in each case based on the weight of the coating agent. cleaning and / or care.
The preferred cleaning and / or care agents contain water in an amount of 0.5 to 98% by weight, particularly preferably 10 to 87% by weight, and most preferably 45 to 80% by weight. % by weight, each time relative to the weight of the cleaning agent and / or care.
shampoos
The preferred cleaning agents according to the invention constitute a shampoo and contain in addition to the at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and the at least one amino acid of the formula (VI): water in an amount of 45 to 98% by weight, particularly preferably 60 to 93% by weight and very preferably 70 to 89% by weight, in each case based on the weight of the cleaning agent, in addition, at least one anionic surfactant in a total amount of 0.1 to 30% by weight, preferably 0.5 to 20% by weight, particularly preferably 1 to 15% by weight, very preferably 3 to 10% by weight, even more preferably 5 to 7% by weight, based on the weight of the cleaning agent, preferably at least one anionic surfactant, selected from alkylpolyglycol ether sulfates and carboxylic acids of ethers each having 10 to 18 carbon atoms arbone in the alkyl group and 2 to 6 ethylene oxide groups in the molecule, the acyl isoethionates having 8 to 24 carbon atoms in the acyl group and the acylated amino acids and the condensation products of acids fatty acids each having 8 to 24 carbon atoms in the acyl group and mixtures of these anionic surfactants, further optionally at least one zwitterionic surfactant in a total amount of 0.1 to 15% by weight, preferably 0 to From 2 to 10% by weight, particularly preferably from 0.5 to 8% by weight, very preferably from 1 to 5% by weight, even more preferably from 2 to 4% by weight, each time on the basis of the weight of the cleaning agent, particularly preferably cocamidopropyl betaine being contained.
Conditioning composition
The preferred care agents according to the invention constitute a rinse-off hair conditioning composition, and additionally contain at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and the at least one amino acid of the formula (VI): water in an amount of 45 to 98% by weight, particularly preferably 60 to 93% by weight and very preferably 70 to 89% by weight, based on the weight of the cleaning agent, in addition at least one cationic surfactant in a total amount of 0.01 to 8% by weight, preferably 0.1 and 6% by weight, particularly preferably 0.5 to 5% by weight. very preferably from 1.0 to 4% by weight, still more preferably from 1.5 to 3.5% by weight, based on the weight of the care agent, preferably at least one surfactant cationic compound chosen from among the quaternary ammonium compounds containing at least one alkyl radical at C8 to C24, the esterquats and the amidoamines each having at least one C8 to C24 acyl radical and mixtures thereof, in addition at least one saturated linear 1-alkanol having 12 to 30 carbon atoms in a total amount of 0.2 10% by weight, particularly preferably from 0.5 to 7% by weight, in each case based on the weight of the care agent, preferably the at least one saturated linear 1-alkanol being contained being selected which is selected from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol and mixtures of these 1-alkanols, optionally further at least one oil in a total amount of 0.01 to 10% by weight, preferably 0.1 to 3% by weight, particularly preferably 0.5 to 1% by weight, each based on the weight of the care agent.
Optionally: polymer A having at least 10 constituent units of the formula (h
The preferred cleaning and / or care agents according to the invention optionally contain at least one polymer A which comprises at least ten constituent units of the formula (I),
Wherein X is nitrogen or oxygen and R 1 and R 2 are each independently hydrogen or C 2 -C 10 acyl or R 1 and R 2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents the oxygen and p is equal to 1 when X represents nitrogen, polymer A does not contain permanently ionic constituents.
Surprisingly, it has been discovered that a polymer A, as mentioned above and explained in more detail hereinafter, remarkably favors the protective and repair effect and the restructuring effect of the cleaning agent. or care of the invention that the combination of at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and / or at least one salt of this acid or acids and at least one amino acid of formula (VI), as explained above, exerts on damaged keratin fibers.
The term "polymer" as used herein means polymers within the meaning of the IUPAC definition which comprise at least 10 identical constituent units.
According to the RÔMPP Chemie Lexikon, from July 2009, according to a definition of IUPAC, a substance is a polymer which consists of a set of macromolecules (polymer molecules) with a chemically homogeneous structure, these macromolecules or polymer molecules being distinguished by their degree of polymerization, molar mass and chain length. In such homogeneous polymer forming substances, all macromolecules have the same structure and differ only in their chain length (degree of polymerization). According to this definition of IUPAC, a polymer is also a "poly-reaction product" which is composed of a large number of molecules in which one or more types of atoms or groups of atoms (called constituent units, base blocks or repeating units) are repeatedly aligned.
The number of constituent units in a polymer is referred to as the degree of polymerization. Preferred polymers A according to the invention as well as polymers B each have a degree of polymerization in the range from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650. Other polymers A preferred according to the invention comprising at least ten constituent units of formula (I) contain 40 to 1000, preferably 100 to 800, particularly preferably 350 to 650, identical constituent units of formula (I). R1 and R2 are preferably and independently hydrogen or a C2-C10 acyl group which is preferably selected from acetyl, propanoyl or n-butanoyl, particularly preferably from acetyl.
The preferred polymers according to the invention comprise at least 10 constituent units of the formula (I) in which X represents nitrogen, the polymer A containing no permanently ionic constituent units. Other particularly preferred polymers according to the invention comprise at least 10 constituent units of the formula (I) wherein X represents nitrogen and R 1 and R 2 together with X form a saturated or unsaturated five or six membered ring which contains optionally other heteroatoms which are preferably selected from N and O, and / or which are optionally substituted with at least one C1 to C6 alkyl group and / or at least one functional group.
When R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O, this ring is preferably substituted by at least one = O functional group. A particularly preferred combination of X, R 1, R 2 substituents is a pyrrolidone group so that a particularly preferred constitutive unit according to the invention of the formula (I) is a unit of the formula (Ia),
wherein X is nitrogen and R1 and R2 together with this nitrogen atom form a five membered saturated ring which does not contain other hetero atoms and which is substituted at the 2-position by a = O functional group.
Another particularly preferred combination of substituents X, R1, R2 is an ε-caprolactam group so that a particularly preferred constitutive unit according to the invention of the formula (I) by a unit of the formula (I b) is,
(Ib). wherein X is nitrogen and R1 and R2 together with this nitrogen atom form a saturated six-membered ring which does not contain other hetero atoms and which is substituted with a = O functional group.
Another particularly preferred combination of X, R 1, R 2 substituents is an imidazole group so that a particularly preferred unit according to the invention of the formula (I) is a unit wherein X is nitrogen and R 1 and R 2 form together with this nitrogen atom a five-membered unsaturated ring which contains nitrogen as another heteroatom. Other preferred polymers according to the invention comprise 25 to 100 mol%, preferably 55 to 100 mol%, particularly preferably 85 to 100 mol%, of constituent units of formula (I) in which X represents the nitrogen, the polymer A containing no permanently ionic constituent units. Other preferred polymers according to the invention comprise 25 to 100 mol%, preferably 55 to 100 mol%, particularly preferably 85 to 100 mol%, of constituent units of formula (I) in which X represents nitrogen and R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms selected from N and O and which is optionally substituted by at least one C1 to C6 alkyl group and or at least one functional group, the polymer A not containing permanently ionic constituent units.
Particularly preferred polymers according to the invention comprise 98 to 100 mol% of constituent units of formula (Ia), polymer A containing no permanently ionic constituent units.
The highly preferred polymers A according to the invention comprise 98 to 100 mol% of constituent units of formula (Ia) and have a degree of polymerization in the range of 40 to 1000, preferably 100 to 800, particularly preferably preferred from 350 to 650, the polymer A not containing permanently ionic constituent units. Especially preferred polymers are homopolymers of polyvinylpyrrolidone having a degree of polymerization in the range of 40 to 1000, preferably 100 to 800, particularly preferably 350 to 650.
Another particularly preferred combination of X, R 1, R 2 substituents is a constituent unit of formula (I) wherein X is oxygen, p is zero and R 1 is hydrogen.
Another particularly preferred combination of X, R 1, R 2 substituents is a unit of formula (I) wherein X is oxygen, p is zero and R 1 is acetyl. Other preferred polymers according to the invention contain 75 to 92 mol% of constituent units of formula (I) in which X is oxygen, p is zero and R 1 is hydrogen and 8 to 25% in moles of constituent units of the formula (I) in which X is oxygen, p is zero and R1 represents an acetyl group, the polymer A containing no permanently ionic constituent units. Other preferred polymers according to the invention contain from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650, constituent units of the formula (I) in which 75 to 92 mol% of constituent units of the formula (I) wherein X represents oxygen, p is zero and R1 is hydrogen and 8 to 25 mol% of constituent units of formula (I) wherein X is oxygen, p is equal to zero and R1 represents an acetyl group, the polymer not containing permanently ionic constituent units. Other polymers A preferred according to the invention contain 65 to 25 mol% of constituent units of formula (la) and 35 to 75 mol% of constituent units of formula (I) in which X is the oxygen, p is zero and R1 represents an acetyl group, the polymer A containing no permanently ionic constituent units. Other preferred polymers A according to the invention contain from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650 constituent units of formula (I), of which 65 to 25 mol% of constituent units of the formula (Ia) and 35 to 75 mol% of constituent units of formula (I) in which X is oxygen, p is zero and R1 is acetyl, polymer A does not contain units constituting permanently ionic. The at least one polymer A having at least ten constituent units of the formula (I) has no permanent ionic charges. However, it is possible that the constituent units of formula (I), for example due to the protonation of the nitrogen atom in an acidic support, are in ionic form, in particular cationic form. These charges are however not permanent, but temporary, because they depend on the surrounding environment.
Preferred cleaning and / or care agents according to the invention contain the at least one polymer A having at least ten constituent units of the formula (I) in a total amount of 0.2 to 5% by weight, preferably from 0.5 to 3% by weight, particularly preferably from 1.0 to 2.3% by weight, in each case based on the weight of the cleaning and / or care agent. Other preferred cleaning and / or care agents contain at least one polymer A having at least ten constituent units of formula (I) chosen from polyvinylpyrrolidone, polyvinyl alcohol, and mixtures thereof, polyvinylpyrrolidone being particularly preferred. Other cleaning and / or care agents which are preferred according to the invention contain at least one polymer A comprising at least ten constituent units of formula (I) in a total amount of 0.2 to 5% by weight, preferably from 0.5 to 3% by weight, particularly preferably from 1.0 to 2.3% by weight, in each case based on the weight of the cleaning and / or care agent, the polymer A being chosen among polyvinylpyrrolidone, polyvinyl alcohol, and mixtures thereof, polyvinylpyrrolidone being particularly preferred.
In addition, it has surprisingly been found that the protection and repair effect and the restructuring effect of the cleaning and / or care agent of the invention and preferred according to the invention, that the combination of at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and / or at least one salt of this acid and these acids and at least one amino acid of the formula (VI), as explained above, exerts on damaged keratin fibers, may further be promoted if at least one compound of the general formula (III) is contained.
The cleaning agents and / or care preferred according to the invention therefore contain (a) at least one compound of the general formula (III)
(III) wherein R1 represents hydrogen or a structural element of formula (IV)
(IV), wherein X is an integer from 1 to 100, the radical R2 in each structural element of formula (IV) may be independently selected from the preceding structural element of formula (IV), R2 is hydrogen, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4- aminobutyl, 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazole-4- 1-methyl, 1H-indol-3-yl-methyl or a (sulfosulfanyl) methyl group, M1 represents the group -OM2 or a structural element of the formula (V)
(V) wherein y is an integer of 1 to 100, the radical R3 in each of the structural elements of formula (V) may be independently selected from a preceding structural element of formula (V), R3 is hydrogen a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazole-4 -ylmethyl, 1H-indol-3-yl-methyl or (sulfosulfanyl) methyl, M2 is hydrogen, or the equivalent of a monovalent or multivalent cation or an ammonium ion (NhU) *.
The essential constituent (a) of the formula (III) is the Bunte salt of an amino acid, an oligopeptide or a peptide which is a compound of the formula (III),
in which R 1 is a hydrogen atom or a structural element of the formula (IV)
(IV) wherein x is an integer from 1 to 100, the radical R2 in each structural element of formula (IV) can be independently selected from the preceding structural element of formula (IV), R2 is hydrogen a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-ylmethyl, a 1H-indol-3-yl-methyl group or a (sulfosulfanyl) methyl group, M1 represents the -OM2 group or a structural element of the formula (V)
(V) wherein y is an integer of 1 to 100 the radical R3 in each of the structural elements of formula (V) can be independently selected from a preceding structural element of formula (V), R3 is hydrogen, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-ylmethyl, a 1H-indol-3-yl-methyl group or a (sulfosulfanyl) methyl group, M2 represents hydrogen, or an equivalent of a monovalent or multivalent cation or an ammonium ion (NH4) +.
The radical R 1 may represent a hydrogen atom or a structural element of the formula (IV)
(IV). The structural element of formula (IV) is further characterized by the repetition index x, where x is an integer from 1 to 100. The repetition index x indicates the number of structural units of the formula (IV ) contained in the compound of formula (III). x is preferably an integer of 1 to 50, more preferably x is an integer of 1 to 20, and most preferably x is an integer of 1 to 10.
If x is, for example, number 10, the compound of formula (III) contains 10 structural units of formula (IV).
It is indispensable here that the R2 radical in each of the structural elements of the formula (IV) can be selected independently of the preceding structural element of the formula (IV). If the compounds of the formula (III) contain, for example, 10 structural units of the formula (IV), these 10 structural units may be the same or different.
The radical R 2 represents a hydrogen atom, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group or a 1-methylpropyl group. hydroxyethyl, a 4-aminobutyl group, a 3-carbamimidamido-propyl group, a 2-carboxyethyl group, a carboxymethyl group, a 2-carbamoylethyl group, a carbamoylmethyl group, a sulfanylmethyl group, a 2- (methylsulfanyl) ethyl group, a 1H-imidazol-4-ylmethyl group, 1H-indol-3-ylmethyl group or (sulfosulfanyl) methyl group. The structural element of formula (IV) is thus an amino acid which is combined by a peptide bond through their amino and / or acid function in the compound of formula (III). If the amino acid is a cysteine, it can also be in the form of a Bunte salt.
If the radical R 2 represents a hydrogen atom, the structural element of the formula (IV) is based on the amino acid glycine.
If the radical R 2 represents a methyl group, the structural element of the formula (IV) is based on the amino acid alanine.
If the radical R 2 is an isopropyl group (i.e., a (H 3 C) 2 CH- group), the structural element of formula (IV) is based on the amino acid valine.
If the radical R 2 represents a 2-methylpropyl group (i.e., a (H 3 C) 2 CH-CH 2 - group), the structural element of the formula (IV) is based on the amino acid leucine.
If the radical R 2 represents a 1-methylpropyl group (that is to say a H 3 C -CH 2 -CH (CH 3) -) group, the structural element of the formula (IV) is based on the amino acid isoleucine .
If the radical R 2 is a benzyl group (i.e. a C 6 H 5 -CH 2 - group), the structural element of the formula (IV) is based on the amino acid phenylalanine.
If the radical R 2 represents a 4-hydroxybenzyl group (ie a 4-OH-C 6 H 5 -CH 2 - group), the structural element of the formula (IV) is based on the amino acid tyrosine.
If the radical R 2 represents a hydroxymethyl group (that is to say a group HO-CH 2 -), the structural element of the formula (IV) rests on the amino acid serine.
If the radical R 2 is 1-hydroxyethyl (i.e., H 3 C -CH (OH) -), the structural element of formula (IV) is based on the threonine amino acid.
If R2 is 4-aminobutyl (i.e., H2N-CH2-CH2-CH2-CH2), the structural element of formula (IV) is based on the amino acid lysine.
If R2 is 3-carbamimidamidopropyl (i.e., H2NC (NH) -NH-CH2CH2CH2-), the structural element of formula (IV) is based on the amino acid arginine.
If the radical R 2 is 2-carboxyethyl (i.e., HOOC-CH 2 -CH 2), the structural element of formula (IV) is based on the amino acid glutamic acid.
If the radical R 2 is a carboxymethyl group (i.e. a HOOC-CH 2 - group), the structural element of the formula (IV) is based on the aspartic acid amino acid.
If the radical R 2 is 2-carbamoylethyl (i.e., H 2 N-C (O) -CH 2 -CH 2 -), the structural element of formula (IV) is based on the amino acid glutamine. .
If the radical R 2 is carbamoylmethyl (i.e., H 2 N-C (O) -CH 2 -), the structural element of formula (IV) is based on the amino acid asparagine.
If the radical R 2 represents a sulfanylmethyl group (i.e., an HS-CH 2 group), the structural element of the formula (IV) is based on the amino acid cysteine.
If the radical R2 is 2- (methylsulfanyl) ethyl (i.e., H3C-S-CH2-CH2), the structural element of the formula (IV) is based on the amino acid methionine.
If the radical R 2 is 1H-imidazol-4-ylmethyl, the structural element of the formula (IV) is based on the amino acid histidine.
If the radical R 2 is 1H-indol-3-ylmethyl, the structural element of formula (IV) is based on the amino acid tryptophan.
Finally, the radical R 2 may be a (sulfosulfanyl) methyl group, a Bunte salt structure of the formula HO-S (O 2) -S-CH 2 -.
Depending on the pH value of the cleaning agent and / or preferred care according to the invention or the composition (A) used according to the invention or preferably according to the invention preferably, the salt structure of Bunte of the formula HO-S (O 2) -S-CH 2 - can also be in their deprotonated form.
In the compound of formula (III), M1 represents the group -OM2 or a structural element of formula (V)
(V). The structural element of the formula (V) is, like the structural element of the formula (IV), characterized by the repetition index y, where y is an integer from 1 to 100. The repetition index y indicates the number of structural units of formula (V) contained in the compound of formula (III).
Preferably, y is an integer of 1 to 50, more preferably y is an integer of 1 to 20, and most preferably y is an integer of 1 to 10.
If there is for example the number 10, the compound of the formula (III) contains 10 structural units of the formula (V).
It is important here that the R3 radical in each of the structural elements of the formula (V) can be selected independently of the previous structural element of the formula (V). If the compounds of the formula (III) contain, for example, 10 units of the formula (V), these 10 structural units may also be the same or different.
The radical R 3 represents a hydrogen atom, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1- hydroxyethyl, 4-aminobutyl group, 3-carbamimidamidopropyl group, 2-carboxyethyl group, carboxymethyl group, 2-carbamoylethyl group, carbamoylmethyl group, sulfanylmethyl group, 2- (methylsulfanyl) ethyl group, 1H group -imidazol-4-ylmethyl, 1H-indol-3-ylmethyl or (sulfosulfanyl) methyl.
Thus, the structural element of formula (V) is also an amino acid which is bound by a peptide bond through their amino function and / or acid function in the compound of formula (III). If the amino acid is a cysteine, it can also be in the form of a Bunte salt.
The radical R 3 represents a hydrogen atom, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1- hydroxyethyl, 4-aminobutyl group, 3-carbamimidamidopropyl group, 2-carboxyethyl group, carboxymethyl group, 2-carbamoylethyl group, carbamoylmethyl group, sulfanylmethyl group, 2- (methylsulfanyl) ethyl group, 1H group -imidazol-4-ylmethyl, 1H-indol-3-ylmethyl or (sulfosulfanyl) methyl. The structural element of formula (IV) is thus an amino acid which is combined by a peptide bond through their amino and / or acid function in the compound of formula (III). If the amino acid is a cysteine, it can also be in the form of a Bunte salt.
If the radical R3 represents a hydrogen atom, the structural element of the formula (IV) is based on the amino acid glycine.
If the radical R3 represents a methyl group, the structural element of the formula (IV) is based on the amino acid alanine.
If the R 3 radical is an isopropyl group (i.e., a (C 1 -C 4 HCl) group), the structural element of the formula (IV) is based on the amino acid valine.
If the radical R 3 is a 2-methylpropyl group (i.e., a (H 3 C) 2 CH-CH 2 - group), the structural element of the formula (IV) is based on the amino acid leucine.
If the radical R 3 represents a 1-methyl-propyl group (that is to say a H 3 C -CH 2 -CH (CH 3) -) group, the structural element of the formula (IV) is based on the amino acid isoleucine .
If the radical R3 is a benzyl group (ie a C6H5-CH2- group), the structural element of the formula (IV) is based on the amino acid phenylalanine.
If the radical R 3 represents a 4-hydroxybenzyl group (that is to say a 4-OH-C 6 H 5 -CH 2 - group), the structural element of the formula (IV) is based on the amino acid tyrosine.
If the radical R3 represents a hydroxymethyl group (that is to say an HO-CHr group). the structural element of formula (IV) is based on the amino acid serine.
If the radical R 3 is 1-hydroxyethyl (i.e., H 3 C -CH (OH) -), the structural element of formula (IV) is based on the threonine amino acid.
If R3 is 4-aminobutyl (i.e., H2N-CH2-CH2-CH2-CH2), the structural element of formula (IV) is based on the amino acid lysine.
If the radical R3 is 3-carbamimidamidopropyl (i.e., H2NC (NH) -NH-CH2CH2CH2-), the structural element of formula (IV) is based on the amino acid arginine.
If the radical R 3 is 2-carboxyethyl (i.e., HOOC-CH 2 -CH 2), the structural element of formula (IV) is based on the amino acid glutamic acid.
If the R 3 radical is a carboxymethyl group (i.e., a HOOC-CH 2 - group), the structural element of the formula (IV) is based on the aspartic acid amino acid.
If the radical R 3 is 2-carbamoylethyl (i.e., H 2 N-C (O) -CH 2 -CH 2 -), the structural element of formula (IV) is based on the amino acid glutamine. .
If the R3 radical is a carbamoylmethyl group (i.e., an H2N-C (O) -CH2- group), the structural element of the formula (IV) is based on the amino acid asparagine.
If the R 3 radical is a sulfanylmethyl group (i.e., an HS-CH 2 group), the structural element of the formula (IV) is based on the amino acid cysteine.
If R3 is 2- (methylsulfanyl) ethyl (ie, H3C-S-CH2-CH2), the structural element of formula (IV) is based on the amino acid methionine.
If the radical R3 is 1H-imidazol-4-ylmethyl, the structural element of the formula (IV) is based on the amino acid histidine.
If the radical R 3 represents a 1H-indol-3-ylmethyl group, the structural element of the formula (IV) is based on the amino acid tryptophan.
Finally, the radical R3 may be a (sulfosulfanyl) methyl group, a Bunte salt structure of the formula HO-S (O 2) -S-CH 2 -.
Depending on the pH value of the cleaning agent and / or preferred care according to the invention or the composition (A) used according to the invention or preferably according to the invention preferably, the salt structure of Bunte of the formula HO-S (O 2) -S-CH 2 - can also be in their deprotonated form.
The radical M2 represents a hydrogen atom, or an equivalent of a monovalent or multivalent cation or an ammonium ion (NH4) +.
Preferred equivalents of a monovalent or multivalent cation include, in particular, sodium and potassium (Na + or K +) or magnesium or calcium (1 / 2Mg2 + or 1 / 2Ca2 +) cations.
If M2 represents a hydrogen atom, then the -OM2 group is the -OH group. If M2 represents a sodium cation, the group -OM2 is the group -ONa. If M2 represents a potassium cation, the group -OM2 is the group -OK. If M2 represents an ammonium ion, the group -OM2 is the group -O (NH4).
The group -OM2 is always adjacent to a carbonyl group. In sum, if M2 represents H, K, Na or ammonium, the compound of formula (III) therefore has an acid in its protonated form or the sodium salt, potassium salt or ammonium salt thereof.
The compounds of the formula (III) of the invention are either the Bunte salt of the cysteine amino acid, the Bunte salts of oligopeptides or the Bunte salts of peptides.
When the radical R 1 represents a hydrogen atom and the radical M 1 represents a group -OM 2, the compound of the formula (III) is then the Bunte salt of the amino acid cysteine. In this case, the compound of formula (III) is the compound of formula (Ilia),
(Ilia) in which M2 is again defined as described above.
If the compound of the formula (Ilia) is in the form of their free acid, it is 2-amino-3- (sulfosulfanyl) propanoic acid. This substance is commercially available.
It has been found that the use of the compound of formula (IIIa) in cleaning and / or care agents, even in particularly low use quantities, results in a particularly effective reduction of hair damage which is always present even after repeated washing. Therefore, the use of compounds of the formula (Ilia) in cleaning and / or care agents is particularly preferred.
In a most particularly preferred embodiment of the invention, a cleaning and / or care agent of the invention is characterized in that it contains at least one compound of formula (III) in which R 1 represents an atom of hydrogen and M1 represents a group -OM2.
When a compound of the formula (Ilia) is used, it is preferably the use of this specific compound. However, if Bunte salts of oligopeptides are used as compounds of formula (III), the cleaning and / or care agent of the invention may also contain several compounds of formula (III) in the form of of a mixture of different oligopeptides. These oligopeptides are defined by their average molecular weight. The average molecular weight Mw of the at least one oligopeptide of formula (III) can be determined for example by gel permeation chromatography (GPC) with polystyrene as internal standard according to DIN 55672-3, version 8/2007. .
Depending on the number of structural units of the formula (III) and / or (IV) contained in the compound of the formula (III), and depending on the type of these amino acids, the molecular weight of the compound of the formula ( III) used according to the invention may vary. It is particularly preferred according to the invention that the compound of formula (III) is an oligopeptide having a molecular weight Mw of 200 to 2000 Da, preferably 250 to 1500 Da, preferably 300 to 1200 Da, in particular 400 at 800 Da.
The term "oligopeptide" in the context of the present invention is understood to mean the condensation products of amino acids which have the aforementioned molecular weights.
In a most particularly preferred embodiment, the cleaning and / or care agent of the invention is characterized in that it contains at least one compound of formula (III) which has a molecular weight Mw of 200 to 2000 Da (Dalton), advantageously from 250 to 1500 Da, preferably from 300 to 1200 Da, in particular from 400 to 800 Da.
If a mixture of oligomers is used in the cleaning and / or care agent of the invention, these mixtures can be defined by their average molecular weight.
In this case, a cleaning agent and / or care of the preferred invention is characterized in that it contains at least one mixture of compounds of formula (III) which has an average molecular weight Mw of 200 to 2000 Da preferably from 250 to 1500 Da, preferably from 300 to 1200 Da, in particular from 400 to 800 Da.
In addition, it has been found that the protective or repairing effect of the compounds of the formula (III) also depends on the x and y repeat indices. As described above, it is most preferred that x be an integer of 1 to 10 and that y be an integer of 1 to 10.
In another particularly preferred embodiment, a cleaning and / or care agent of the invention characterized in that it contains at least one compound of the formula (III) in which R 1 represents a structural element of the formula (IV), and M1 represents a structural member of the formula (V), and x is an integer of 1 to 10 and y is an integer of 1 to 10.
In addition to the molecular weight of the compound of formula (III), the proportion of Bunte salt units, which are contained in the compound of formula (III), also have a decisive influence on the effectiveness of the protective effect or the "repair effect" of the compounds.
Compounds having at least one Bunte salt unit, for example that present in the compound of the formula (Ilia), are very effective, especially when used as a monomeric compound. Oligopeptides having at least one Bunte salt unit are particularly effective when they have a low molecular weight of up to 1200, in particular 800 daltons.
However, when using oligopeptides, it is particularly advantageous that the compound of formula (III) has at least two, preferably at least three, Bunte salt units.
In another particularly preferred embodiment, a cleaning and / or care agent of the invention is characterized in that it contains at least one compound of the formula (III) in which R 1 represents a structural element of the formula (IV), and the radical R 2 in the at least one structural element of formula (IV) represents a (sulfosulfanyl) methyl group (i.e., for example, a group H0-S (O 2) -S CH2 -) -
In another particularly preferred embodiment, a cleaning and / or care agent of the invention is characterized in that it contains at least one compound of the formula (III) in which R 1 represents a structural element of the formula (IV), and x is an integer of at least 3, and R2 in at least 3 structural members of formula (IV) is a 2-carboxyethyl group (i.e., a HOOC group -CH2-CH2).
In another very particularly preferred embodiment, a cleaning and / or care agent of the invention is characterized in that it contains at least one compound of the formula (III) in which M 1 represents a structural element of the formula (V), and y is an integer equal to at least 3, and the radical R3 in at least 3 structural elements of formula (IV) is a group (Glu). The at least one compound of formula (III) is contained, based on the total weight of the cleaning agent and / or care preferred according to the invention, in a total amount of 0.001 to 5% by weight. Surprisingly, however, it has been found that the compound (s) of formula (III) can cause a very good reduction in hair damage already at low concentrations. This is particularly advantageous if the at least one compound of formula (III) is to be added to the cleaning and / or care agent of the invention as an additive (for example in the form of a care solution or a repair solution) before applying to the hair. For this reason, it is particularly advantageous that the preferred cleaning and / or care agent according to the invention contains one or more compounds of the above-mentioned formula (III) in a total amount of 0.001 to 2.5% by weight, more preferably from 0.005 to 0.2% by weight and particularly preferably from 0.01% to 0.07, in each case based on the weight of the cleaning and / or care agent of the invention.
In another particularly preferred embodiment, a cleaning and / or care agent of the invention is characterized in that it contains one or more compounds of the formula (III) mentioned above, preferably in a total amount of 0.001. at 2.5% by weight, more preferably from 0.005 to 0.2% by weight and particularly preferably from 0.01 to 0.07% by weight, in each case based on the weight of the cleaning agent and or care of the invention.
In another particularly preferred embodiment, a cleaning and / or care agent of the invention is characterized in that it has a pH value in the range of 3.0 to 7.5, preferably 3.5 to 6.5, particularly preferably 4.0 to 5.5, each measured at 20 ° C.
Another object of the present application is a method for cleaning and / or caring for keratin fibers, in particular human hair, in which a cleaning or care agent of the invention or preferred according to the invention, as described above, is applied to the keratin fibers, in particular to human hair, and optionally removed by rinsing after an action time of 0.1 to 60 minutes, preferably 0.5 to 15 minutes, so particularly preferred from 1 to 10 minutes.
Another object of the present application is a method for cleaning and / or caring for keratin fibers, in particular human hair, comprising the following steps: I. producing a composition (A) containing at least one saturated dicarboxylic acid having 2 to 10 carbon atoms in a total amount of 2 to 20% by weight, preferably 5 to 15%, particularly preferably 8 to 12% by weight, each converted to undissociated acid and on the based on the weight of the composition (A), the dicarboxylic acid being preferably selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and mixtures of these acids, succinic acid and malic acid being particularly preferred, succinic acid being very preferred, in addition at least one amino acid of the formula (V I)
(VI) wherein X represents a hydrogen atom or a monovalent or divalent cation; n is zero, 1.2 or 3; R 1 represents a radical which is selected from an amino group, a guanidine group, a (1H-imidazol-4-yl) group, a carboxylic acid amide group -CONH 2, a 1H-indol-3-yl group, a thiol group -SH and a methylsulfanyl group -SCH3, or at least one salt of this amino acid [0003] and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably from 0.8 to 5.0% by weight, particularly preferably from 1.5 to 4.0% by weight, each time converted to the undissociated acid and on the basis of the weight of the composition (A) preferably at least one of the amino acids arginine, histidine or lysine and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, particularly preferably from 1.5 to 4.0% by weight, in each case converted to undissociated acid and on the basis of the weight of the composition (A), and water, preferably in a amount of 50 to 92% by weight of particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight, each on the basis of the weight of the composition (A), optionally furthermore at least one polymer A which comprises at least at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six-membered saturated or unsaturated ring elements which optionally contain other heteroatoms which are preferably selected from N and O, and / or optionally substituted with at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p = 1, when X represents nitrogen, the polymer A containing no permanently ionic constituent units, preferably the at least one polymer A being contained in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case relative to the weight of the composition (A), the composition (A) having preferably a pH value in the range of 3.5 to 7.1, d preferably from 4.5 to 6.5, particularly preferably from 5.0 to 6.0, each measured at 20 ° C, water and optionally additionally at least one substance which is selected from the compounds of the general formula (III),
(III) wherein R1 represents a hydrogen atom or a structural element of formula (IV)
(IV) wherein x represents an integer from 1 to 100, the radical R2 in each structural element of formula (IV) can be independently selected from the preceding structural element of formula (IV), R2 represents hydrogen a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, , 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-yl- methyl, a 1H-indol-3-ylmethyl group or a (sulfosulfanyl) methyl group, M1 represents the group -OM2 or a structural element of the formula (V)
(V) wherein y is an integer of 1 to 100, the radical R3 in each of the structural elements of formula (V) may be independently selected from a preceding structural element of formula (V), R3 is hydrogen a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-ylmethyl , a 1H-indol-3-yl-methyl group or a (sulfosulfanyl) methyl group, M2 represents hydrogen, or an equivalent of a monovalent or multivalent cation or an ammonium ion (NhU) *, preferably one or several compounds of the aforementioned formula being contained in ns a total amount of 0.01 to 2.5% by weight, more preferably 0.05 to 0.5% and particularly preferably 0.1 to 0.3% by weight, in each case with respect to weight of the composition (A), and polymers A comprising at least ten constituent units of the formula (I),
(I) wherein X is nitrogen or oxygen, and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a saturated or unsaturated five or six-membered ring; elements which may optionally contain other heteroatoms which are preferably selected from N and O and / or which are substituted by at least one C1-C6 alkyl group and / or at least one functional group and p = 0 when X represents oxygen and p = 1 when X represents nitrogen, the polymer A containing no permanently ionic constituent units, preferably the at least one polymer A is contained in a total amount of 0.5 to 14% by weight. weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case relative to the weight of the composition (A), II. producing a cleaning and / or care composition (B) containing at least one cleaning and / or care agent, selected from surfactants, fatty alcohols and oils, optionally water and III. mix the compositions (A) and (B) together, and just after IV. apply the mixture of (A) and (B) on the keratin fibers, in particular on the human hair, V. optionally rinsing off after a time of action of 0.1 to 60 minutes, preferably 0.5 at 15 minutes, particularly preferably from 1 to 10 minutes, VI. possibly perform other hair treatments, such as conditioning and / or drying.
What has just been said for the cleaning agents and / or care of the invention applies mutatis mutandis to the cleaning composition and / or care (B) in terms of water content, surfactant content, fatty alcohol content and oil content.
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the composition (A) intended for hair treatment containing: at least one saturated dicarboxylic acid having 2 to 10 carbon atoms in a total amount from 2 to 20% by weight, preferably from 5 to 15%, particularly preferably from 8 to 12% by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), dicarboxylic acid being preferably selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and mixtures of these acids, at least one amino acid of the formula (VI) and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0 to , 8 to 5.0%, particularly preferably 1.5 to 4.0% by weight, at each converted into the undissociated acid and on the basis of the weight of the composition (A), and water, preferably in an amount of 50 to 92% by weight, particularly preferably 60 to 87% by weight. weight and very preferably from 65 to 80% by weight, in each case relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at least one saturated dicarboxylic acid having 2 to 10 carbon atoms in a total amount of 2 to 20% by weight, preferably 5 to 15%, particularly preferably 8 to 12% by weight, each converted to undissociated acid and based on the weight of the composition (A), dicarboxylic acid being preferably selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, acid sebacic acid, and mixtures of these acids, at least one of the amino acids arginine, histidine or lysine and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0, 8 to 5.0% by weight, particularly preferably 1.5 to 4.0% by weight each time converted to the undissociated acid and on the basis of the weight of the composition (A), and 50 to 92% by weight, particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight of water, in each case relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at least one saturated dicarboxylic acid having 2 to 10 carbon atoms in a total amount of 2 to 20% by weight, preferably 5 to 15%, particularly preferably 8 to 12% by weight, each converted to undissociated acid and based on the weight of the composition (A), dicarboxylic acid being preferably selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, acid sebacic acid, and mixtures of these acids, furthermore at least one amino acid of the formula (VI) and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0%, particularly preferably 1.5 to 4.0% by weight, at each It is converted into the undissociated acid and on the basis of the weight of the composition (A), in addition to water, preferably in an amount of 50 to 92% by weight, particularly preferably from 60 to 87% by weight. by weight and very preferably from 65 to 80% by weight, in each case relative to the weight of the composition (A), and at least one polymer A which comprises at least ten constituent units of the formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is 1 when X is nitrogen, Polymer A does not contain permanently ionic units, in the composition (A) in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at each converted to the undissociated acid and on the basis of the weight of the composition (A) 2 to 20% by weight, preferably 5 to 15% by weight, particularly preferably 8 to 12% by weight, succinic acid, in addition at least one of the amino acids arginine, histidine or lysine and or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, particularly preferably 1.5 to 4.0%. by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), and 50 to 92% by weight, particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight of water, in each case relative to the weight of the composition (A), in addition at least one polymer A which comprises at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is 1 when X is nitrogen, Polymer A does not contain permanently ionic units, in the composition (A) in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at each converted to the undissociated acid and on the basis of the weight of the composition (A) 2 to 20% by weight, preferably 5 to 15% by weight, particularly preferably 8 to 12% by weight, of malic acid, in addition at least one of the amino acids arginine, histidine or lysine and or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, particularly preferably 1.5 to 4.0%. by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), and 50 to 92% by weight, particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight of water, in each case relative to the weight of the composition (A), in addition at least one polymer A which comprises at least at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is 1 when X is nitrogen, Polymer A does not contain permanently ionic units, in the composition (A) in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at each converted to the undissociated acid and on the basis of the weight of the composition (A) 2 to 20% by weight, preferably 5 to 15% by weight, particularly preferably 8 to 12% by weight, succinic acid, in addition at least one of the amino acids arginine, histidine or lysine and or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, particularly preferably 1.5 to 4.0%. by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), and 50 to 92% by weight, particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight of water, in each case relative to the weight of the composition (A), in addition at least one polymer A which comprises at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is equal to 1 when X represents nitrogen, polymer A containing no permanently ionic constituent units and being chosen from polyvinylpyrrolidone, polyvinyl alcohol, and mixtures thereof, polyvinylpyrrolidone being particularly preferred, in the composition (A) in a total amount of from 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, each time relative to the weight of the composition (A).
Another subject of the present invention relates to a method for cleaning and / or caring for keratin fibers, the hair treatment composition (A) containing: at each converted to the undissociated acid and on the basis of the weight of the composition (A) 2 to 20% by weight, preferably 5 to 15% by weight, particularly preferably 8 to 12% by weight, of malic acid, in addition at least one of the amino acids arginine, histidine or lysine and or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, particularly preferably 1.5 to 4.0%. by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), and 50 to 92% by weight, particularly preferably from 60 to 87% by weight and very preferably from 65 to 80% by weight of water, in each case relative to the weight of the composition (A), in addition at least one polymer A which comprises at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is equal to 1 when X represents nitrogen, polymer A containing no permanently ionic constituent units and being chosen from polyvinylpyrrolidone, polyvinyl alcohol, and mixtures thereof, polyvinylpyrrolidone being particularly preferred, in the composition (A) in a total amount of from 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, each time relative to the weight of the composition (A).
Polymer A, contained in compositions (A) preferably used according to the invention, comprises at least ten constituent units of formula (I),
(I) wherein X is nitrogen or oxygen and R1 and R2 are each independently hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and p = 0 when X represents oxygen and p is equal to 1 when X represents nitrogen, polymer A does not contain permanently ionic constituent units.
Surprisingly, it has been discovered that a polymer A, as mentioned above and explained in more detail hereinafter, remarkably favors the protective and repair effect and the restructuring effect of the cleaning agent. or care of the invention that the combination of at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and / or at least one salt of this acid or acids and at least one amino acid of formula (VI), as explained above, exerts on damaged keratin fibers.
The term "polymer" as used herein means polymers within the meaning of the IUPAC definition which comprise at least 10 identical constituent units.
According to the RÔMPP Chemie Lexikon, from July 2009, according to a definition of IUPAC, a substance is a polymer which consists of a set of macromolecules (polymer molecules) with a chemically homogeneous structure, these macromolecules or polymer molecules being distinguished by their degree of polymerization, molar mass and chain length. In such homogeneous polymer forming substances, all macromolecules have the same structure and differ only in their chain length (degree of polymerization). According to this definition of IUPAC, a polymer is also a "poly-reaction product" which is composed of a large number of molecules in which one or more types of atoms or groups of atoms (called constituent units, base blocks or repeating units) are repeatedly aligned.
The number of constituent units in a polymer is referred to as the degree of polymerization. Preferred polymers A according to the invention as well as polymers B each have a degree of polymerization in the range from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650. Other polymers A preferred according to the invention comprising at least ten constituent units of formula (I) contain 40 to 1000, preferably 100 to 800, particularly preferably 350 to 650, identical constituent units of formula (I). R 1 and R 2 are preferably and independently hydrogen or a C 2 -C 10 acyl group which is preferably selected from acetyl, propanoyl or n-butanoyl, particularly preferably from acetyl.
The preferred polymers according to the invention comprise at least 10 constituent units of the formula (I) in which X represents nitrogen, the polymer A containing no permanently ionic constituent units. Other particularly preferred polymers according to the invention comprise at least 10 constituent units of the formula (I) wherein X represents nitrogen and R 1 and R 2 together with X form a saturated or unsaturated five or six membered ring which contains optionally other heteroatoms which are preferably selected from N and O, and / or which are optionally substituted with at least one C1 to C6 alkyl group and / or at least one functional group.
When R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms which are preferably selected from N and O, this ring is preferably substituted by at least one = O functional group. A particularly preferred combination of X, R 1, R 2 substituents is a pyrrolidone group so that a particularly preferred constitutive unit according to the invention of the formula (I) is a unit of the formula (Ia),
wherein X is nitrogen and R1 and R2 together with this nitrogen atom form a five membered saturated ring which does not contain other hetero atoms and which is substituted at the 2-position by a = O functional group.
Another particularly preferred combination of substituents X, R1, R2 is an ε-caprolactam group so that a particularly preferred constitutive unit according to the invention of the formula (I) by a unit of the formula (I b) is,
(Ib), wherein X is nitrogen and R1 and R2 together with this nitrogen atom form a saturated six-membered ring which does not contain any other hetero atoms and which is substituted with a = O functional group.
Another particularly preferred combination of X, R 1, R 2 substituents is an imidazole group so that a particularly preferred unit according to the invention of the formula (I) is a unit wherein X is nitrogen and R 1 and R 2 form together with this nitrogen atom a five-membered unsaturated ring which contains nitrogen as another heteroatom. Other preferred polymers according to the invention comprise 25 to 100 mol%, preferably 55 to 100 mol%, particularly preferably 85 to 100 mol%, of constituent units of formula (I) in which X represents the nitrogen, the polymer A containing no permanently ionic constituent units.
Other preferred polymers according to the invention comprise 25 to 100 mol%, preferably 55 to 100 mol%, particularly preferably 85 to 100 mol%, of constituent units of formula (I) in which X represents nitrogen and R1 and R2 together with X form a five or six membered saturated or unsaturated ring which optionally contains other heteroatoms selected from N and O and which is optionally substituted by at least one C1 to C6 alkyl group and or at least one functional group, the polymer A not containing permanently ionic constituent units.
Particularly preferred polymers according to the invention comprise 98 to 100 mol% of constituent units of formula (Ia), polymer A containing no permanently ionic constituent units.
The highly preferred polymers A according to the invention comprise 98 to 100 mol% of constituent units of formula (Ia) and have a degree of polymerization in the range of 40 to 1000, preferably 100 to 800, particularly preferably preferred from 350 to 650, the polymer A not containing permanently ionic constituent units. Particularly preferred polymers A are homopolymers of polyvinylpyrrolidone having a degree of polymerization in the range of 40 to 1000, preferably 100 to 800, particularly preferably 350 to 650.
Another particularly preferred combination of X, R 1, R 2 substituents is a constituent unit of formula (I) wherein X is oxygen, p is zero and R 1 is hydrogen.
Another particularly preferred combination of X, R 1, R 2 substituents is a unit of formula (I) wherein X is oxygen, p is zero and R 1 is acetyl. Other preferred polymers according to the invention contain 75 to 92 mol% of constituent units of formula (I) in which X is oxygen, p is zero and R 1 is hydrogen and 8 to 25% in moles of constituent units of the formula (I) in which X is oxygen, p is zero and R1 represents an acetyl group, the polymer A containing no permanently ionic constituent units. Other preferred polymers according to the invention contain from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650, constituent units of the formula (I) in which 75 to 92 mol% of constituent units of the formula (I) wherein X represents oxygen, p is zero and R1 is hydrogen and 8 to 25 mol% of constituent units of formula (I) wherein X is oxygen, p is equal to zero and R1 represents an acetyl group, the polymer not containing permanently ionic constituent units. Other polymers A preferred according to the invention contain 65 to 25 mol% of constituent units of formula (la) and 35 to 75 mol% of constituent units of formula (I) in which X is the oxygen, p is zero and R1 represents an acetyl group, the polymer A containing no permanently ionic constituent units. Other preferred polymers A according to the invention contain from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650 constituent units of formula (I), of which 65 to 25 mol% of constituent units of the formula (Ia) and 35 to 75 mol% of constituent units of formula (I) in which X is oxygen, p is zero and R1 is acetyl, polymer A does not contain units constituting permanently ionic. The at least one polymer A having at least ten constituent units of the formula (I) has no permanent ionic charges. However, it is possible that the constituent units of formula (I), for example due to the protonation of the nitrogen atom in an acidic support, are in ionic form, in particular cationic form. These charges are however not permanent, but temporary, because they depend on the surrounding environment.
The preferred compositions (A) used according to the invention contain at least one polymer A comprising at least ten constituent units of the formula (I). Other preferred compositions (A) used according to the present invention contain at least one polymer A comprising at least ten constituent units of formula (I) in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight , in each case relative to the weight of the composition (A), said polymer A being chosen from polyvinylpyrrolidone, polyvinyl alcohol and mixtures thereof, polyvinylpyrrolidone being particularly preferred.
The carriers for cleaning and / or care agents of the invention may be solid, liquid, pasty or in gel form. They are preferably chosen from aqueous systems, natural or synthetic oils, water-in-oil or oil-in-water emulsions. Such systems and methods for preparing them are known in the state of the art referred to herein. The preparations may be formulated as a cream, a gel or a liquid. In addition, it is possible to make the agents in the form of aerosol foams which are placed in aerosol containers with foaming valve with a liquefied gas such as propane and butane mixtures, nitrogen CO2, air, NO2, dimethyl ether, chlorofluorocarbon propellants or mixtures thereof. The individual components of the process of the invention are preferably used in the form of cream, gel or liquid. In addition, the preparations of the invention may be present in two or more phases. Two or more phase systems are systems in which at least two separate continuous phases are present. For example, an aqueous phase and one or more, for example two non-aqueous, immiscible phases between them are present separately from each other in such systems. For example, a water-in-oil emulsion, and an aqueous phase separately thereof, or a water-in-oil emulsion and an aqueous phase present separately therefrom are also possible.
In another embodiment of the invention, the preparation may contain a complexing agent such as EDTA, NTA, β-alaninediacetic acid, a phosphonic acid or mixtures of these substances. Other suitable active substances are the polyols such as glycerol and the partial ether of glycerol, in particular 3 - [(2-ethylhexyl) oxy] -1,2-propanediol, 2-ethyl-1,3- hexanediol, 1,3-butanediol, 1,4-butanediol, 1,2-propanediol, 1,3-propanediol, pentanediols, for example 1,2-pentanediol, hexanediol such as 1, 2-hexanediol or 1,6-hexanediol, dodecanediols, especially 1,2-dodecanediol, neopentyl glycol and ethylene glycol. In particular, 2-ethyl-1,3-hexanediol, 1,2-propanediol, 1,3-propanediol and 1,3-butanediol have proved particularly suitable.
These polyols are contained in the compositions of the invention and used according to the invention, preferably in a total amount of 0.1 to 10%, in particular from 0.5 to 5% by weight, relative to the total preparation. .
According to the invention, it is of course also possible to use miscible alcohols only in a limited manner with water, in particular when it is necessary to obtain multi-phase systems.
By "miscible only to a limited extent with water" is meant alcohols which are soluble in water at 20 ° C to not more than 10% by weight, based on the mass of the water.
As fatty acids, linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms may be used in amounts of 0.1 to 15% by weight relative to the total agent. Fatty acids are monocarboxylic acids.
In addition, it has been shown that the polymers are advantageously used in the context of the process of the invention. In a preferred embodiment, polymers are therefore added to the preparations used according to the invention, the cationic, anionic, amphoteric and also nonionic polymers having proved effective.
Cationic polymers are understood to mean the polymers which comprise in the main and / or side chain a group which may be "temporarily" or "permanently" cationic. "Cationic permanently" according to the invention means polymers which comprise a group. cationic regardless of the pH value of the preparation. These are generally polymers which contain a quaternary nitrogen atom, for example in the form of an ammonium group. Preferred cationic groups are quaternary ammonium groups. In particular, the polymers in which the quaternary ammonium group is linked via a C1-C4 hydrocarbon group to a main polymer chain consisting of acrylic acid, methacrylic acid or derivatives thereof have been found particularly suitable.
Homopolymers of the general formula (IX),
wherein R 1 = -H or -CH 3, R 2, R 3 and R 4 are independently selected from hydroxyalkyl, alkenyl and C 1 -C 4 alkyl, m = 1, 2, 3 or 4, n is a natural number and X 'is a physiologically acceptable organic or inorganic anion, and the copolymers, consisting essentially of monomeric units expressed in formula (II) and nonionic units, are particularly preferred cationic polymers. In the context of these polymers, those according to the invention are those for which at least one of the following conditions is fulfilled: R 1 is a methyl group, R 2, R 3 and R 4 are methyl groups at a value of 2.
Suitable physiologically acceptable counterions X 'are, for example, halide ions, sulfate ions, phosphate ions, methosulphate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Halide ions, in particular chloride, are preferred.
A particularly suitable homopolymer is methacryloyloxyethyltrimethylammonium polychloride, optionally crosslinked, having the INCI name Polyquatemium-37. The crosslinking can be carried out if desired using olefinically polyunsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallylether, polyallylpolyglycerylether, or allylethers of sugars or sugar derivatives such as erythritol. , pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylenebisacrylamide is a preferred crosslinking agent.
The homopolymer is preferably used in the form of a non-aqueous polymer dispersion whose proportion of polymer must not be less than 30%. These polymer dispersions are sold under the names Salcare®95 (proportion of polymers of approximately 50%, other components: mineral oil (INCI name: Ore Oil) and tridecyl-polyoxypropylene-polyoxyethylene-ether (INCI name: PPG- 1-Trideceth-6)) and Salcare®SC 96 (polymer proportion about 50%, other components: mixture of propylene glycol diesters with a mixture of caprylic and capric acids (INCI name: Propylene Glycol Dicaprylate / dicaprate), and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI name: PPG-1-Trideceth-6)) are commercially available.
The copolymers having monomer units according to the formula (G1-I) contain, as non-ionogenic monomer units, preferably acrylamide, methacrylamide, C1-C4 alkyl esters of acrylic acid and the alkyl esters thereof. C1-4 methacrylic acid. Among these nonionic monomers, acrylamide is particularly preferred. These copolymers may also be crosslinked as described above in the case of homopolymers. A preferred copolymer according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers, in which the monomers are present in a weight ratio of about 20:80, are commercially available in the form of a non-aqueous dispersion of about 50% polymers under the name Salcare®SC 92. Other preferred cationic polymers are, for example, quaternized cellulose derivatives, such as those commercially available under the names Celquat® and Polymer®R®. The compounds Celquat®H 100, Celquat®L 200 and Polymer JR®400 are preferred derivatives of quaternized cellulose, - cationic alkylpolyglycosides according to DE-PS 44 13 686, - cationized honey, for example the commercial product Honeyquat ®50, - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia®Guar and Jaguar®, - polysiloxanes having quaternary groups, such as commercially available products Q2-7224 (manufacturer: Dow Corning, a stabilized trimethylsilylamodimethicon), Dow Coming®929 Emulsion (containing a hydroxylamino-modified silicone, which is also known as amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ®-Quat 3270 and 3272 (manufacturer: Th. Goldschmidt), diquaternary polydimethylsiloxanes, Quaternium-80), - dimethyldiallylammonium salts polymers and their copolymers with esters and mides of acrylic acid and methacrylic acid.
The products commercially available under the names Merquat® 100 (dimethyldiallylammonium polychloride) and Merquat®550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of these cationic polymers, the copolymers of vinylpyrrolidone with quaternized derivatives of the acrylate and dialkylaminoalkyl methacrylate, such as, for example, vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the trade names Gafquat®734 and Gafquat®755, vinylpyrrolidone-vinylimidazolium methochloride copolymers, such as those offered under the names Luviquat® FC 370, FC 550, FC 905 and HM 552, quaternized polyvinyl alcohol, and quaternary nitrogen atom polymers in the main polymer chain, known as Polyquaternium 2, Polyquaternium 17, Polyquaterna 18 and Polyquaterna 27.
It is also possible to use, as cationic polymers, the polymers known under the names Polyquatemium-24 (commercial product, for example by Quatrisoft®LM 200). Vinylpyrrolidone copolymers such as those available as commercial products Copolymer 845 (ISP manufacturer), Gaffix®VC713 (manufacturer: ISP), Gafquat® ASCP 1011, Gafquat® HS 110, Luviquat® 8155 and the like can also be used according to the invention. Luviquat®MS 370. Other cationic polymers of the invention are so-called "temporarily cationic" polymers. These polymers usually contain an amino group which are present at specific pH values in the form of a quaternary ammonium group and thus in cationic form. The preferred ones are, for example, chitosan and their derivatives, for example those freely available commercially, for example under the trade names Hydagen®CMF, Hydagen®HCMF, Kytamer®PC and Chitolam®N / 101.
According to the invention, the preferred cationic polymers are the cationic derivatives of cellulose and chitosan and its derivatives, in particular the commercial products Polymer®JR 400, Hydagen®HCMF and Kytamer®PC, the cationic derivatives of guar, the derivatives cationic honey, in particular the commercial product Honeyquat® 50, the cationic alkylpolyglycoside according to DE-PS 44 13 686 and the polymers of the Polyquaternium-37 type.
Likewise, the use of vitamins, provitamins and vitamin precursors and their derivatives has proved advantageous.
The vitamins, provitamins and vitamin precursors preferred according to the invention are those which are commonly associated with groups A, B, C, E, F and H.
The group of substances designated by vitamin A includes retinol (vitamin A1) and 3,4-didehydroretinol (vitamin A2). Β-carotene is the provitamin of retinol. The vitamin A component is according to the invention for example retinoic acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate. The formulations used in the present invention include the vitamin A component in amounts of 0.05 to 1% by weight based on the total preparation.
The group vitamin B or vitamin B complex includes among others - vitamin B1 (thiamine) - vitamin B2 (riboflavin) - vitamin B3. This designation frequently includes nicotinic acid and nicotinamide (niacinamide) compounds. According to the invention, the preference is given to nicotinamide which is preferably present in the agents used according to the invention in amounts ranging from 0.05 to 1% by weight relative to all the agent. - vitamin B5 (pantothenic acid, panthenol and pantolactone). In this group, panthenol and / or pantolactone are preferably used. The panthenol derivatives that may be used according to the invention are the panthenol esters and ethers and the cationically derived panthenols. The individual representatives are, for example, panthenol, panthenol and its monoacetates and the cationic derivatives of panthenol disclosed in WO 92/13829. The mentioned compounds of vitamin B5 type are present in the agents used according to the invention, preferably in amounts of 0.05 to 10% by weight, relative to the total agent. Quantities of 0.1 to 5% by weight are particularly preferred. vitamin B6 (pyridoxine as well as pyridoxamine and pyridoxal).
Vitamin C (ascorbic acid). Vitamin C is preferably used in the agents used according to the invention in amounts of 0.1 to 3% by weight, based on the total agent. Use in the form of palmitic acid ester, glucosides or phosphates may be preferred. Use in combination with tocopherols may also be preferred.
Vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, by which in particular esters such as acetate, nicotinate, phosphate and succinate, are contained in the compositions intended for the cosmetic process according to the invention and the use according to the invention of preferably in amounts of 0.05 to 1% by weight, based on the entire composition.
Vitamin F. The term "vitamin F" is usually understood to mean essential fatty acids, especially linoleic acid, linolenic acid and arachidonic acid.
Vitamin H. Vitamin H denotes the acid compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid, for which the trivial name of biotin has meanwhile been adopted. The biotin is contained in the compositions for the cosmetic processes according to the invention and the use according to the invention preferably in amounts of 0.0001 to 1.0% by weight, in particular in amounts of 0.001 to 0. , 01% by weight.
Preferably, the preparations used according to the invention contain vitamins, pro-vitamins and vitamin precursors of groups A, B, E and H. Of course, several vitamins and vitamin precursors may be present at the same time. Panthenol, pantolactone, pyridoxine and its derivatives as well as nicotinamide and biotin are particularly preferred.
Finally, the agents of the invention may contain plant extracts.
In addition, suitable conditioning substances are silicone gums and cationic silicones such as commercially available products Q2-7224 (manufacturer: Dow Corning a stabilized trimethylsilylamodimethicone), Dow Corning®939 Emulsion (containing a modified hydroxylamino silicone, also called amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil®-Quat 3270 and 3272 (manufacturer: Th. Goldschmidt, diquaternary polydimethylsiloxanes, Quaternium-80). An appropriate anionic silicone oil is Dow Corning®1784. Other substances, auxiliaries and additives are for example thickeners, such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum flax, dextrans, cellulosic derivatives, for example methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such as bentonite, perfume oils - solvents and solubilizers such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, - pearlescent agents such as mono and ethylene glycol distearate and PEG-3-distearate, - pigments, - propellants such as mixtures of propane and butane, N20, dimethyl ether, CO 2 and air, - antioxidants
Examples:
The following agents of the invention were prepared (quantitative data in percent by weight): a) Color protection shampoo and repair of hair structure
The oxidation-colored hair has, after repeated cleaning (10 to 20 cleanings) with the shampoos above, a brilliant color whose resistance properties do not vary significantly. In addition, the hair washed with the shampoos above have a visually appealing gloss and a particularly soft feel. b) Conditioning composition with rinsing (conditioner, quantities in percentage by weight)
c) Method according to the invention of restructuring the hair with a shampoo of the invention the following compositions (A) were prepared (quantitative data in percentage by weight):
The following shampoo composition (B-1) was prepared (quantitative data by weight):
5 grams of the composition (A-1) was mixed with 50 grams of the hair conditioning composition (B-2); then, the mixture was applied to wet hair, massaged for 0.5 minutes, allowed to act for 1 minute and then rinsed with water. 5 grams of the composition (A-2) was mixed with 50 grams of the hair conditioning composition (B-1); then, the mixture was applied to wet hair, massaged for 0.5 minutes, then rinsed with water. d) Process according to the invention of restructuring hair care with a hair conditioning composition with rinsing of the invention a hair conditioning composition with rinsing (B-2) (quantitative data in percentage by weight) was prepared:
5 grams of the composition (A-1) was mixed with 50 grams of the hair conditioning composition (B-2); then, the mixture was applied to wet hair, massaged for 0.5 minutes, allowed to act for 1 minute and then rinsed with water. 5 grams of the composition (A-2) was mixed with 50 grams of the hair conditioning composition (B-2); then, the mixture was applied to wet hair, massaged for 0.5 minutes, allowed to act for 1 minute and then rinsed with water.

权利要求:
Claims (13)
[1" id="c-fr-0001]
claims
1. Cosmetic cleaning and / or care agent for keratin fibers, in particular human hair, which is free of peroxide compounds, containing a. at least one saturated dicarboxylic acid having 2 to 10 carbon atoms and / or at least one salt of this acid or acids, furthermore b. at least one amino acid of the formula (VI)

(VI) wherein X represents a hydrogen atom or a monovalent or divalent cation; n is zero, 1.2 or 3; R 1 represents a radical which is selected from an amino group, a guanidine group, a (1H-imidazol-4-yl) group, a carboxylic acid amide group -CONH 2, a 1H-indol-3-yl group, a group thiol -SH and a methylsulfanyl -SCH3 group, or at least one salt of this amino acid, further c. at least one active cleaning and / or care substance selected from surfactants, fatty alcohols and oils.
[2" id="c-fr-0002]
2. cleaning or care agent according to claim 1, characterized in that the at least one saturated dicarboxylic acid having 2 to 10 carbon atoms are selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and mixtures of these acids, preferably among succinic acid and malic acid, particularly preferably succinic acid.
[3" id="c-fr-0003]
3. Cleaning or care agent according to claim 1 or 2, characterized in that the at least one saturated dicarboxylic acid having 2 to 10 carbon atoms is contained in a total amount of 0.05 to 6% by weight, preferably from 0.1 to 4% by weight, particularly preferably from 0.5 to 2.5% by weight, each converted to the undissociated acid and on the basis of the weight of the cleaning agent and or care.
[4" id="c-fr-0004]
4. Cleaning or care agent according to one of claims 1 to 3, characterized in that the at least one amino acid of formula (VI) is chosen from arginine, lysine, histidine, asparagine, glutamine, cysteine, methionine, tryptophan and mixtures thereof, particularly preferably mixtures of arginine and lysine.
[5" id="c-fr-0005]
5. cleaning or care agent according to one of claims 1 to 4, characterized in that the at least one amino acid of formula (VI) is contained in a total amount of 0.05 to 3% by weight preferably from 0.1 to 2.5% by weight, particularly preferably from 0.3 to 1.2% by weight, in each case converted to the undissociated acid and on the basis of the weight of the cleaning and / or care agent.
[6" id="c-fr-0006]
6. Cleaning or care agent according to one of claims 1 to 5, characterized in that it contains at least one compound of the general formula (III)

(III) wherein R1 represents hydrogen or a structural element of formula (IV)

(iv), wherein X is an integer from 1 to 100, the R2 radical in each structural element of the formula (IV) can be independently selected from the preceding structural element of the formula (IV), R2 represents the hydrogen, a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, 3-carbamimidamido-propyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-yl methyl, a 1H-indol-3-ylmethyl group or a (sulfosulfanyl) methyl group, M1 represents the group -OM2 or a structural element of the formula (V)

(V) wherein y is an integer of 1 to 100, the radical R3 in each of the structural elements of formula (V) may be independently selected from a preceding structural element of formula (V), R3 is hydrogen , a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, a 3-carbamimidamido-propyl group, 2-carboxyethyl group, carboxymethyl group, 2-carbamoylethyl group, carbamoylmethyl group, sulfanylmethyl group, 2- (methylsulfanyl) ethyl group, 1H-imidazol-4-ylmethyl group, a 1H-indol-3-yl-methyl group or a (sulfosulfanyl) methyl group, M2 represents hydrogen, or an equivalent of a monovalent or multivalent cation or an ammonium ion (NhU) *, preferably, one or several compounds of the above-mentioned formula (III) being in a total amount of from 0.001 to 2.5% by weight, more preferably from 0.005 to 0.2% by weight and particularly preferably from 0.01% to 0.07, in each case based on the weight of cleaning agent and / or care of the invention.
[7" id="c-fr-0007]
7. Cleaning or care agent according to one of claims 1 to 6, characterized in that it contains at least one polymer A which comprises at least ten constituent units of the formula (I),

(I) wherein - X represents nitrogen or oxygen and - R1 and R2 each independently represent hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a saturated or unsaturated five or five-membered ring; six elements which optionally contains other heteroatoms which are preferably selected from N and O and / or which are optionally substituted by at least one C1-C6 alkyl group and / or at least one functional group, and - p = 0 when X represents oxygen and p is equal to 1 when X represents nitrogen, polymer A containing no permanently ionic constituent units, the at least one polymer A comprising at least ten constituent units of formula (I) ) preferably in a total amount of 0.2 to 5% by weight, particularly preferably from 0.5 to 3% by weight, very preferably from 1.0 to 2.3% by weight, each time relative to the weight of the cleaning agent or s anoint.
[8" id="c-fr-0008]
8. A cleaning or care agent according to claim 7, characterized in that the at least one polymer A comprising at least two constituent units of the formula (I) is chosen from polymers which comprise 98 to 100 mol% of constituent units of the formula (la)

(1a) and which each have a degree of polymerization in the range of from 40 to 1000, preferably from 100 to 800, particularly preferably from 350 to 650, the polymer A containing no permanently ionic constituent units.
[9" id="c-fr-0009]
9. A method for cleaning and / or caring for keratin fibers, in particular human hair, in which a cleaning or care agent according to one of claims 1 to 8 is applied to the keratin fibers, in particular on human hair, and optionally removed by rinsing after an action time of 0.1 to 60 minutes, preferably from 0.5 to 15 minutes, particularly preferably from 1 to 10 minutes.
[10" id="c-fr-0010]
A method of cleaning and / or caring for keratin fibers, in particular human hair, comprising the following steps: I. producing a composition (A) containing - at least one saturated dicarboxylic acid having 2 to 10 carbon atoms carbon in a total amount of 2 to 20% by weight, preferably 5 to 15%, particularly preferably 8 to 12% by weight, each time converted to undissociated acid and on the basis of the weight of the composition (A), the dicarboxylic acid being preferably selected from succinic acid, malic acid, oxalic acid, malonic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and mixtures of these acids, succinic acid and malic acid being particularly preferred, succinic acid being very preferred, furthermore at least one amino acid of formula (VI)

(VI) wherein X represents a hydrogen atom or a monovalent or divalent cation; n is zero, 1, 2 or 3; R 1 represents a radical which is selected from an amino group, a guanidine group, a (1H-imidazol-4-yl) group, a carboxylic acid amide group -CONH 2, a 1H-indol-3-yl group, a thiol group; -SH and a methylsulfanyl -SCH3 group, or at least one salt of this amino acid and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, more preferably 1.5 to 4.0% by weight, each converted to the undissociated acid and based on the weight of the composition (A), preferably at least one of the amino acids arginine, histidine or lysine and / or a salt thereof in a total amount of 0.4 to 7.0% by weight, preferably 0.8 to 5.0% by weight, so particularly preferably from 1.5 to 4.0% by weight, in each case converted to the undissociated acid and on the basis of the weight of the composition (A), and - water, preferably in a quantity of 50 to 92% by weight, so 60 to 87% by weight and more preferably 65 to 80% by weight, in each case based on the weight of the composition (A); optionally furthermore at least one polymer A which comprises at least ten constituent units of formula (I),

(I) wherein - X represents nitrogen or oxygen and - R1 and R2 each independently represent hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a saturated or unsaturated five-membered ring; or six elements which optionally contains other heteroatoms which are preferably selected from N and O, and / or optionally substituted with at least one C1-C6 alkyl group and / or at least one functional group, and - p = 0 when X represents oxygen and p = 1, when X represents nitrogen, polymer A containing no permanently ionic constituent units, preferably the at least one polymer A being contained in a total amount of 0.5 at 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case based on the weight of the composition (A), the composition (A) ) preferably having a pH value in the range of 3.5 to 7.1, preferably 4.5 to 6.5, particularly preferably 5.0 to 6.0, each measured at 20 ° C, water and optionally in addition at least one substance which is selected from - the compounds of the general formula (III),

(III) wherein R1 represents a hydrogen atom or a structural element of formula (IV)

(IV) wherein x represents an integer from 1 to 100, the radical R2 in each structural element of formula (IV) can be independently selected from the preceding structural element of formula (IV), R2 represents hydrogen , a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, a 3-carbamimidamidopropyl, 2-carboxyethyl, carboxymethyl, 2-carbamoylethyl, carbamoylmethyl, sulfanylmethyl, 2- (methylsulfanyl) ethyl, 1H-imidazol-4-ylmethyl , a 1H-indol-3-yl-methyl group or a (sulfosulfanyl) methyl group, M1 represents the group -OM2 or a structural element of the formula (V)

(V) wherein y is an integer of 1 to 100, the radical R3 in each of the structural elements of formula (V) may be independently selected from a preceding structural element of formula (V), R3 is hydrogen , a methyl group, an isopropyl group, a 2-methylpropyl group, a 1-methylpropyl group, a benzyl group, a 4-hydroxybenzyl group, a hydroxymethyl group, a 1-hydroxyethyl group, a 4-aminobutyl group, a 3-carbamimidamidopropyl group, 2-carboxyethyl group, carboxymethyl group, 2-carbamoylethyl group, carbamoylmethyl group, sulfanylmethyl group, 2- (methylsulfanyl) ethyl group, 1H-imidazol-4-ylmethyl group, 1H-indol-3-yl-methyl group or (sulfosulfanyl) methyl group, M2 represents hydrogen, or an equivalent of a monovalent or multivalent cation or an ammonium (NH4) + ion, preferably one or more compounds of the above-mentioned formula being contained in s a total amount of 0.01 to 2.5% by weight, more preferably 0.05 to 0.5% and particularly preferably 0.1 to 0.3% by weight, in each case with respect to weight of the composition (A), and - polymers A comprising at least ten constituent units of the formula (I),

(I) wherein - X represents nitrogen or oxygen, and - R1 and R2 each independently represent hydrogen or a C2-C10 acyl group or R1 and R2 together with X form a saturated or unsaturated five-membered ring; or six elements which may optionally contain other heteroatoms which are preferably selected from N and O and / or which are substituted by at least one C1-C6 alkyl group and / or at least one functional group and - p = 0 when X represents oxygen and p = 1 when X represents nitrogen, polymer A containing no permanently ionic constituent units, preferably the at least one polymer A is contained in a total amount of 0.5 to 14% by weight, preferably from 1.0 to 11% by weight, particularly preferably from 2.0 to 10% by weight, in each case based on the weight of the composition (A), II. producing a cleaning and / or care composition (B) containing at least one cleaning and / or care agent selected from surfactants, fatty alcohols and oils, optionally water and III. mix the compositions (A) and (B) together, and just after IV. apply the mixture of (A) and (B) on the keratin fibers, in particular on the human hair, V. optionally rinsing off after a time of action of 0.1 to 60 minutes, preferably 0.5 at 15 minutes, particularly preferably from 1 to 10 minutes, VI. possibly perform other hair treatments, such as conditioning and / or drying.
[11" id="c-fr-0011]
11. Cleaning and / or care agent according to one of claims 7 to 8 or process according to claim 9 or 10, characterized in that at least one polymer A, which comprises at least ten constituent units of the formula ( I) and which does not contain permanently ionic constituent units, is chosen from polyvinylpyrrolidone, polyvinyl alcohol, and mixtures thereof, polyvinylpyrrolidone being particularly preferred.
[12" id="c-fr-0012]
12. Method according to one of claims 9 to 11, characterized in that the composition (B) is a shampoo containing: - water in an amount of 45 to 98% by weight, particularly preferably 60 to 93 % by weight and very preferably 70 to 89% by weight, in each case based on the weight of the cleaning agent, in addition to at least one anionic surfactant in a total amount of 0.1 to 30% by weight. weight, preferably from 0.5 to 20% by weight, particularly preferably from 1 to 15% by weight, very preferably from 3 to 10% by weight, even more preferably from 5 to 7% by weight on the basis of the weight of the cleaning agent, preferably at least one anionic surfactant, selected from alkylpolyglycol ether sulfates and carboxylic acid ethers each having 10 to 18 carbon atoms in the alkyl group and 2 to 6 groups of ethylene oxide in the molecule, isoethi acyl onates having 8 to 24 carbon atoms in the acyl group and acylated amino acids and fatty acid condensation products of proteins each having 8 to 24 carbon atoms in the acyl group and mixtures of these surfactants anionic, additionally optionally at least one zwitterionic surfactant in a total amount of 0.1 to 15% by weight, preferably from 0.2 to 10% by weight, particularly preferably from 0.5 to 8% by weight. weight, more preferably from 1 to 5% by weight, still more preferably from 2 to 4% by weight, each based on the weight of the cleaning agent, particularly preferably cocamidopropyl betaine being contained.
[13" id="c-fr-0013]
13. Method according to one of claims 9 to 11, characterized in that the composition (B) is a rinse-containing hair conditioning composition containing: - water in an amount of 45 to 98% by weight, particularly preferably from 60 to 93% by weight and very preferably from 70 to 89% by weight, based on the weight of the cleaning agent, in addition - at least one cationic surfactant in a total amount of 0.01 at 8% by weight, preferably from 0.1 to 6% by weight, particularly preferably from 0.5 to 5% by weight, very preferably from 1.0 to 4% by weight, even more preferred from 1.5 to 3.5% by weight, based on the weight of the care agent, preferably at least one cationic surfactant selected from quaternary ammonium compounds having at least one C 8 alkyl radical C24, esterquats and amidoamines each having at least one C8 to C24 acyl radical and their further comprising: - at least one saturated linear 1-alkanol having 12 to 30 carbon atoms in a total amount of 0.2 to 10% by weight, particularly preferably 0.5 to 7% by weight, in each case based on the weight of the care agent, preferably the at least one saturated linear 1-alkanol being selected being selected which is selected from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol and mixtures of these 1-alkanols, in addition - optionally at least one oil in a total amount of 0.01 to 10% by weight, preferably 0.1 at 3% by weight, particularly preferably from 0.5 to 1% by weight, each on the basis of the weight of the care agent.

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同族专利:

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公开号 | 公开日

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DE102015223196A1|2017-05-24|

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法律状态:
2017-11-21| PLFP| Fee payment|Year of fee payment: 2 |

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2019-11-20| PLFP| Fee payment|Year of fee payment: 4 |

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2021-08-06| ST| Notification of lapse|Effective date: 20210705 |

优先权:

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申请号 | 申请日 | 专利标题

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DE102015223196.8A|DE102015223196A1|2015-11-24|2015-11-24|Agents and methods for cleaning and / or caring for damaged keratinic fibers|

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